Chemistry Paper 2 Flashcards
What is the formula for a mean rate of reaction in terms of reactants?
quantity of reactant used/time taken
What is the formula for a mean rate of reaction in terms of products?
quantity of reactant product formed/time taken
How can you measure the quantity of a reactant or product?
In grams or in cm3
What are the two possible units for rate of reaction?
g/s or cm3/s (where s is seconds)
How could you measure the rate of a reaction from a graph?
Draw a tangent to the curve and calculate the gradient.
What is “collision theory”?
The theory that chemical reactions only occur when particles collide with sufficient energy
What five factors can affect the rate of a reaction?
Temperature, surface area of a solid, concentration of reactants in solution, pressure of gases, catalyst
State the effect of increasing the surface area on the rate of a reaction
Increases the rate
Explain why increasing the surface area increases the rate of a reaction
More particles are available to collide there are therefore more frequent collisions between reactants.
State the effect of increasing the concentration on the rate of reaction
Increases
Explain why increasing the concentration increases the rate of reaction
More concentrated means more particles in solution, therefore more frequent collisions between reactants.
State the effect on increasing the pressure of a gas on the rate of reaction
Increases
Explain why increasing the pressure of a gas increases the rate of a reaction
Less space for the particles to move around in, therefore more frequent collisions
State the effect of increasing the temperature on the rate of reaction
Increases
What is the activation energy?
The amount of energy a particle needs before it will be able to react when it collides with another particle
Explain why increasing the temperature increases the rate of reaction
Increases the speed at which particles move therefore more frequent collisions.
Increases the number of particles which have the activation energy therefore more collisions result in a reaction.
What is a catalyst?
Something which changes the rate of a reaction but is not used up in that reaction
How do catalysts speed up reactions?
They provide another route for the reaction to take place which has a lower activation energy.
What is a reversible reaction?
A reaction which can go from reactants to products but also from products to reactants
What chemical symbol represents a reversible reaction?
⇌
If a reaction is exothermic in the forward direction what will it be in the reverse direction?
Endothermic
What is dynamic equilibrium?
The point in a reversible reaction when the forward and reverse reactions are occurring at the same rate
How is the amount of reactant changing at equilibrium?
It is not changing
How is the amount of product changing at equilibrium?
It is not changing
(HT) What is Le Chatelier’s principle?
When a reaction at equilibrium is changed, it will seek to counteract that change
(HT) A reaction is exothermic in the forward direction. What will occur if the temperature is increased?
The backward reaction will increase as it is endothermic and will reduce the temperature
(HT) A reaction is at equilibrium when some product is removed. What will occur?
The forward reaction will increase as that will increase the amount of product
(HT) How does increasing the pressure affect equilibrium?
Favours the side with fewer gaseous molecules
What is crude oil?
A mixture of hydrocarbons
What is a finite resource?
One that will run out
Why is crude oil a finite resource?
Because it takes longer to form than the rate at which we are using it up
What is a hydrocarbon?
A compound made of atoms of carbon and hydrogen only
What is a general formula?
A mathematical formula which allows you to work out the chemical formula of a substance
What is an alkane?
A hydrocarbon with only single bonds
Name the first four alkanes
Methane, ethane, propane, butane
What is the general formula for alkanes?
Cn + H2n+2
How does boiling point change with the length of an alkane?
The longer the alkane, the higher its boiling point
How does viscosity change with the length of an alkane?
The longer the alkane, the more viscous (the thicker) it is
How does flammability change with the length of an alkane?
The longer the alkane, the less flammable it is
What is fractional distillation?
A process used to separate mixtures substances with different boiling point
What are the steps involved in fractional distillation?
Crude oil is vaporised, different molecules rise up the fractionating column and cool down. Condense at different points on the column.
Why is fractional distillation important?
Because the different fractions have different uses
What is a fuel?
A substance which when reacted with oxygen releases energy
Name five fuels we obtain from crude oil
Petrol, diesel, kerosene, heavy fuel oil and liquefied petroleum gases
What other uses are there for products of fractional distillation?
Solvents, lubricants, polymers and detergents
What is combustion?
The reaction of a fuel with oxygen
What are the products of complete combustion?
Carbon dioxide and water
When does incomplete combustion occur?
When there is not enough oxygen present
What is cracking?
The process of breaking down a long hydrocarbon into smaller hydrocarbons
What are the products of cracking?
Short alkanes and alkenes
Why is cracking important?
Because smaller hydrocarbons are more useful than longer ones
What are the two types of cracking?
Catalytic and steam cracking