Chemistry In Industry (The Contact Process, Electrolysis Of Brine) Flashcards
Step 1. Sulfur is oxidised
Sulfur + Oxygen –>
Sulfur dioxide
Step 2. Sulfur dioxide is oxidised
Sulfur dioxide + Oxygen –>
Sulfur Trioxide
Step 3. Sulfur trioxide is dissolved in concentrated sulfuric acid
Sulfur trioxide + Sulfuric acid –>
Oleum
Oleum is diluted with measure amount of water
Oleum + Water –>
Concentrated sulfuric acid
Step 1 equation:
Sulfur + Oxygen –> Sulfur dioxide
S + O2 –> SO2
Step 2 equation:
Sulfur dioxide + Oxygen –> Sulfur trioxide
2SO2 + O2 –> 2SO3
Step 3 equation:
Sulfur trioxide + sulfuric acid –> Oleum
SO3 + H2SO4 –> H2S2O7
Step 4 equation:
Oleum + water –> Concentrated sulfuric acid
H2S2O7 + H2O –> 2H2SO4
Oleum equation
H2S2O7
Sulfuric acid
2H2SO4
Conditions for the contact process:
Temperature:
Pressure:
Catalyst:
Temperature: 450C
Pressure: 2 atmospheres
Catalyst: Vanadium oxide (V2O5)
Uses of sulfuric acid
Fertilisers
Detergents
Paints
Concentrated brine is electrolysed industrially using a ____________ cell
Diaphragm
What is in brine
Sodium chloride
What three products are produced from the electrolysis of brine
Hydrogen gas
Chlorine gas
Sodium hydroxide
Chlorine gas is given off at the _________
Anode
Hydrogen gas is given off at the _________
Cathode
The sodium ions stay in the solution and the hydroxide ions from the water are also left behind. What does this mean
Sodium hydroxide solution is left in the solution
Half equation at the cathode
2H+ + 2e- –> H2
Half equation at the anode
2Cl- –> Cl2 + 2e-
Useful products from the electrolysis of brine and their uses
Chlorine - Sterilising water supplies. Bleach.
Hydrogen - Used in the haber process
Sodium hydroxide - Soap, bleach
Use of chlorine
Sterilising water supplies. Bleach
Use of Hydrogen
Used in the haber process
Use of sodium hydroxide
Soap, bleach