Chemistry 7-Rate of Reaction Flashcards

1
Q

Rate of reaction depends on what 4 things

A

Temperature
Catalyst
Concentration (pressure for gasses)
Surface area of solids(smaller bits higher rate)

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2
Q

Rate of reaction =

A

amount used or formed / time

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3
Q

How does the precipitation method of observing rate of reaction work?

A

Observe a mark on a beaker and wait until you cant see it anymore

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4
Q

Change in mass is measured how?

A

Production of a gas leads to a decrease in the mass of a scale

The quicker the readings drop the faster the reaction

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5
Q

Name one more more method of observing rate of reaction

A

Volume of gas given off

Using syringe

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6
Q

If you were to double the quantity of small chips present in a HCl solution, what happens?

A

Quicker reaction

More gas created

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7
Q

Which method would you use for HCl and Marble Chips

A

Volume given off (Syringe)

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8
Q

Which method would you use for magnesium metal and HCl

A

Mass scales + gas given off

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9
Q

why is the mass scale method good?

A

Can help work out the measuring effects of increased concentration as H+ is given off

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10
Q

Sodium Thiosulfate + HCl produce what precipitate

A

Cloudy yellow

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11
Q

sodium thiosulfate and HCl are what colour?

A

clear

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12
Q

What can we do with the sodium thiosulphate and HCl reaction when repeating it?

A

Use of different temperatures via a waterbath

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13
Q

What is the precipiate formed with sodium thiosulphate and HCl

A

Sulphur

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14
Q

Hydrogen peroxide breaks down into what?

A

Water / oxygen

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15
Q

What 3 things can speed up the rate of reaction with hydrogen peroxide breakdown

A

Manganse (IV) oxide catalyst

Potato Peel

Blood

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16
Q

Name the main benefit from an industrial point of view on catalyst

A

Never get used up in the reaction

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17
Q

What can poison the iron catalyst in the Haber process?

A

sulphur impurities

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18
Q

Name an example of an exothermic reaction

A

Burning fuels (Combustion)

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19
Q

Acid + Alkali are what type of reaction?

A

Exothermic

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20
Q

Sodium and water is what type of reaction

A

exothermic

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21
Q

Handwarmers use what to generate heat

A

oxidation of iron in air

with salt solution catalyst to generate heat

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22
Q

Thermal decomposition is what type of reaction

A

Endothermic

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23
Q

Give an example of a endothermic reaction in practical use

A

Sports injury pack

They take in heat which makes the pack very cold

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24
Q

What must be supplied to decompose calcium carbonate?

What sort of reaction is this?

A

Heat

Endothermic reaction

25
Hydrated copper sulphate --> anhydrous copper sulphate and water what type of reaction?
Endothermic
26
Anhydrous Copper sulphate + water -->Hydrate copper sulphate what type of reaction
exothermic
27
Heating blue copper (2) sulphate turns it what colour?
White
28
Bond breaking is what type of reaction
endothermic
29
bond formation is what type of reaction
exothermic
30
In an endothermic reaction, the energy required to break old bonds is what?
Greater than the energy released when new bonds are formed
31
In an exothermic reaction, the energy released in bond formation is what?
Greater than the energy used in breaking old bonds
32
How can you measure the amount of energy released in a chemical reaction?
taking temperature of the reagents at start / and at end
33
What method is used to measure the amount of energy released?
Polysteyrene cup + beaker of cotton wool and a lid
34
What type of reactions is using the polysteryne cup good for?
Solids with water neutralisation reactions
35
Working out using Calorimetry equation
mass of water x specific heat capacity (4.2) x change in temperature
36
In exothermic reactions, the reactants always have what?
more starting energy hence -H
37
In endothermic reactions, the products always have what?
Greater initial energy hence +H
38
Dynamic equiibrium is what
Where both sides of the reaction are happening simultaneously but no overall net change
39
Equilibrium in a reaction only happens in what type of system?
Closed system
40
What 3 things can change equilibrium?
Temperature pressure concentration
41
Adding a catalyst doesnt do what
change the equilibrium position
42
Decreasing the temperature of a reaction, will shift the equilibrium why
Moves in to exothermic direction to produce more heat
43
Increasing the temperature causes the equilibrium to move where
endothermic direction to try and decrease the temperature
44
Changing pressure only affects what
gases
45
Increasing the pressure changes the equilibrium how and why
It tries to reduce it by moving equilibrium in the direction where there are fewer molecules (the side with less moles)
46
Increasing the concentration of the reactants will do what to the equilibrium?
Tries to decrease it by making more product (shifts to the right)
47
Increasing the concentration of a product will do what to equilibrium?
Shift to the left by creating more reactant
48
Nitrogen and Hydrogen form what
Ammonia
49
Hydrogen can be obtained how?
Natural gas / crude oil
50
With the haber process, which is the exothermic reaction?
forward reaction
51
What happens in the Haber process when increasing pressure?
More ammonia formed increased %yield
52
Lowering the temperature does what for the reaction?
Increases the yield (favours exothermic reaction) However it takes longer
53
what is the correct temperature for Haber
450*
54
Ammonia is formed as what? What happens to the nitrogen/hydrogen
Formed as gas then cooled to form liquid recycled
55
What catalyst is used in the haber process? what does it NOT change
iron catalyst decreases the temperature required
56
Whats the ideal conditions for the Haber process?
High pressure and low temperature
57
Draw the % yield of ammonia to pressure
=
58
Draw the % yield of ammonia to temperature
=