chemical reactivity, metal extraction, acid base salt Flashcards
Metal + acid ->
Salt + hydrogen
Metal oxide + acid ->
Salt + water
Metal hydroxide + acid ->
salt + water
Metal carbonate + acid ->
salt + carbon dioxide + water
Define saturated solution
A solution that can hold no more solute / solid at the specified temperature
What is an acid?
A proton donor
What is difference between weak and strong acids?
1) Strong acids fully ionise
2) Weak acid partially ionise
The ionisation of a strong acid is shown by using a → in the equation, showing it is non-reversible
The ionisation of a weak acid is shown by using a rightwards harpoon over leftwards harpoonin the equation, showing it is reversible
H2SO3 (reversible arrow sign) HSO3– + H+
Hydorchloric acid
HCL
What is a base? in terms of particles
Protons acceptors
Define water of crystallisation
Water molecules present in hydrated crystals
What are amphoteric oxides?
Oxides that react with acids & bases the same.
Both reaction produce salt and water
Are metal oxides base or acidic?
Metal oxides are usually basic
Give examples of amphoteric oxides
Aluminum oxide Al2O3
Zinc oxide ZnO
When hydrochloric acid dissolves into water the acid compound ionises
give ionic equation
HCL(aq) —> H+ (aq) + CL- (aq)
Sulfuric acid formula
H2SO4
Ammonia formula
NH3
Aqueous solutions of acids contain
H+ ions
Aqueous solutiosn of base contain
OH- ions
Litmus paper with acid
Red
Litmus paper with base
Blue
Thymolphthalein with acid
Colourless
Methyl Orange with base
Red
Methyl orange with acid
Yellow
Neutralisation reaction between acid and alkaline to produce water ionic equation
H+ (aq) + OH-(aq) -> H2O(L)
Base vs alkali
Base are oxides or hydroxides of metals
Alkali are soluble bases
List the reactivity series
Please - Potassium
Stop - Sodium
Calling - Calcium
Me - Magnesium
A - Aluminium
Careless - Carbon
Zebra - Zinc
Instead - Iron
Try - Tin
Learning - Lead
How - Hydrogen
Copper - Copper
Saves - Silver
Gold -Gold
Group 1 reactions with cold water
More fire and explosives as you go down the group
reaction of magnesium with steam
Magnesium burns in steam to produce white magnesium oxide and hydrogen gas
Neutralisation equation
acid + alkali = salt + water
define ionise
When ions in an ionic solid separate during dissolving
When an alkali like sodium hydroxide dissolves give ionic equation
NaOH -> Na+ + OH-
The strength of an acid is also a measure of…
How much the acid compound ionises
Strong acid will… [2]
Fully ionise
Completely disasscoiate in water
Weak acid will… [2]
Partially ionise
partially dissociate in water
Ethanoic acid (Vinegar) & Citric acid weak or strong
Weak acid
Good method writing [5]
1) Start each step with a command word (Measure, pour etc)
2) Include at least 2 control variables
3) Include measurements
4) Include scientific equippments
5) Include repeats for the same measurements to identify anomalies and calculate a mean
Calculate mass of water from using crystallisation
Mass of hydrated salt - mass of anhydrous salt
Define Precipitation
2 soluble ionic salts are combined, they can form an insoluble salt, a precipitate
How is Calcium oxide manufactured from limestone
By thermal decomposition of calcium carbonate
Slag
the substance that is formed when impurities in the ore react with calcium hydroxide (Limewater)
What gas do K, Li, and Na release when reacting with water
Hydrogen
Non-metal oxides are acidic or alkaline
Acidic
Ammonium chloride + Base =
Ammonia
Name of aluminium ore
Bauxite
What is another name for iron ore
Hematite
Limestone largely contains…
Calcium carbonate
Two functions of the coke used in the blast furnace are
1) To provide heat
2) To produce carbon dioxide
Limewater is another name for..
aqueous solution of calcium hydroxide
Making salt practical using sulfuric acid and copper oxide [7]
1)Measure 20ml of sulfuric acid
2) Add copper oxide in excess and stir
3) Filter the mixture
4) Place filtrate into evaporating basin
5) Heat gently on yellow flame
6) Stop heating when the liquid has reduced by half
7)Leave the mixture to dry on drying rack and crystalise
Make salt from sulfuric acid and Copper oxide word equation
Sulfuric acid + copper oxide -> copper sulfat + water
How to know if gas is sulfur dioxide?
1) Add permenganate paper
2) Turn purple to colourless
How to know if gas is ammonia?
1) Add damp red litmus paper
2) Turns blue (Ammonia is an alkali/base)
Sulfite vs sulfate
sulfite ion is SO32- and a sulfate ion is SO42-
How to know if gas is carbon dioxide?
1) Bubble gas through limewater
2) White precipitate of calcium carbonate forms and turns lime water cloudy white
How to know if gas is chlorine?
1) Add damp blue litmus paper
2) Turns bleach
How to know if gas is oxygen?
1) Add a glowing splint
2) Relights
Flame test barium
Light green
Flame test calcium
Orange-red
Flame test copper(II)
Blue - green
Flame test sodium
yellow
Flame test potassium
lilac
Flame test lithium
Red
How to test for metal ions? [2]
1) Add sodium hydroxide solution
2) Add ammonium NH3
How to test for negative ion (Anion) [4]
1) Carbonates test
2) Halides test
3) Sulphate test
4) Nitrate test
Describe carbonates test
1) Add dilute acid to a carbonate
2) It should fizz and produce carbon dioxde
Describe halides (Group 7) test
1) Add nitric acid then add silver nitrate
2) Chlorides = white precipitate
3) Bromides = Cream precipitate
4) Iodides (Anion with valency of -1) = Pale yellow precipitate
Describe sulphate test
1) Add dilute hydrochloric acid then barium chloride solution
2) White precipitate to show sulphate ions presence
Describe nitrates test
1) Aluminium foil + Sodium hydroxide
2) Ammonia gas
Define displacement
When a more reactive element swaps places with a less reactive element in a compound
What is released when acid dissoaciates in water?
protons are released when an acid dissociates in water
All sodium, potassium and ammonium salts are soluble or insoluble
soluble
All nitrates are soluble or insoluble
soluble
Most chlorides, bromides, and iodies (Halides) are soluble or insoluble
Soluble
Most sulphates, except lead, barium, and calcium are soluble or insoluble
soluble
Sodium, potassium, and ammonium carbonates are soluble or insoluble
soluble
Sodium, potassium, ammonium, and calcium hydroxide are soluble or insoluble
soluble
Silver and lead halides are soluble or insoluble
insoluble
lead, barium, and calcium sulphate are soluble or insoluble
insoluble
Most carbonates, except sodium, potassium, and ammonium are soluble or insoluble
insoluble
Most hydroxides, except sodium, potassium, and ammonium are soluble or insoluble
insoluble
Gas test hydrogen
ignites easily and will burn with a ‘squeaky pop’
Iron(II) and Iron(III) colours and acid used
Iron(II) forms green precipitate
Iron(III) forms brown precipitate
uses sodium hydroxide
How many different salts could be made from a supply of dilute sulfuric acid, dilute hydrochloric
acid, copper, magnesium oxide and zinc carbonate?
4 because copper doesnt really react with dilute acids
A pungent smelling gas is produced when ammonium carbonate is added. base or acid
Base
Reaction of metal oxide with carbon makes a metal more or less reactive
Less reactive because its being replaced in displacement reaction
How is carbon dioxide converted into carbon monoxide in the blast furnace?
Carbon dioxide reacts with coke
Write the chemical equation of calcium oxide with silicon(IV) oxide and state the type of reaction
CaO + SiO2 -> CaSiO3
Acid-base reaction
Why must the high levels of carbon be lowered before the iron becomes a useful material?
Iron becomes too brittle
How is carbon removed from the iron?
By oxygen blowing in
Equvilance point definition
include graph
point in titration at which the amount of titrant added is just enough to completely neutralize the solution.
(Graph will show sharp increase at one point)
Ore definition
Rock containing enough metal to make it worthwhile extracting
Word equation of the extraction of iron from iron oxide include which gets oxidised and reduced
Iron oxide + carbon -> Iron + carbon dioxide
Carbon gains oxygen oxidation
Iron loses oxygen reduction
Define thermal decomposition
Chemical decompisiton by heat
Tin nitrate thermal decompose to? Sn(NO3)4
SnO2 + NO2
Name an acidic and alkaline oxide
`1) CO2 is acidic
2) NaO alkaline
Are non metal oxides acidic or basic
Usually acidic
Copper (II) colour
Lilac
How are metals above carbon in reactivity series extracted
Electrolysis
How are metals below carbon in reactivity series extracted
Displacement
1 use of slaked lime
cement
How to get hydrogen gas from metals in the reactivity series and hydrochloric acid?
All metals more reactive than hydrogen will release hydrogen when reacting with hydrochloric acid
How to test anhydrous copper (II) sulphate with water
White (dry) to blue (water)