Chemical Kinetics Flashcards

1
Q

arrhenius equation

A

k=Ae^-Ea/RT

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2
Q

how do we find the temperature from the arrhenius equation

A

T2= [1/T1- Rln(K2/K1)/Ea]-1

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3
Q

on what order reaction does the change in the concentration of the inital reactant affect the reaction?

A

Every reaction except Zero order

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4
Q

define rate law

A

It is an equation that tells us how the rate of reaction depends on the concentration of the reactants at a particular moment

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4
Q

define zero order reaction

A

It is a reaction that does not depend on the concentration of the reactants

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4
Q

define rate law

A

It is an equation that tells us how the rate of reaction depends on the concentration of the reactants at a particular moment

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4
Q

write the rate law expression

A

rate= k[A]^x[B]^y

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5
Q

is the order of the reaction necessarily the same as the stoichiometric coefficients in the balanced equation?

A

no

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5
Q

write the integrated rate law for the zero order reaction.

A

[A] t =−kt +[A]

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5
Q

define the first order reaction

A

it is a reaction where the rate of reaction depends on the concentration of reactants by a power of one

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5
Q

write the integrated rate equation for the first order reaction

A

ln [A]final=-kt+ln[A]initial

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6
Q

what is chemical kinetics

A

it is the area of chemistry that studies how fast a reaction goes or in other words the rate reaction

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7
Q

what is the rate of reaction?

A

It is the change in concentration of the reactant or a product over a given period of time

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8
Q

what is the unit of rate of reaction?

A

mol L–1 s–1

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9
Q

list factors affecting the rate of reaction

A

nature of reactants
concentation of reactants
surface area

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10
Q

True or False
The acid-base reaction of HCl and NaOH is much faster than the decomposition of
hydrogen peroxide,

A

True

11
Q

True or False
The reaction of calcium with cold water is moderate

A

TRUE

12
Q

A reaction between substances that are in different physical phases (solid, liquid, gas) is
called a ___________ reaction

A

heterogeneous

13
Q

When the size of particles is minimized, contact between the
atoms, ions, or molecules in the solid state also minimizes with those in a different phase.

A

False
It maximizes contact

14
Q

A reaction of substances when both are in the gaseous or liquid phase, is referred to as
a _____________ reaction.

A

homogeneous