carboxylic acid Flashcards

1
Q

Define carboxylic acid

A

they are **organic **compounds that contain at least one carboxyl group in the structire.

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2
Q

what is a carboxyl group?

define the consistent molecule

A

it is functional group consisting of a carboxyl and a hydroxyl

s usually written as —COOH or —CO2
H

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3
Q

the general formula for saturated monocarboxylic acid is

A

double bond of oxygen on carbon and an OH on carbon

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4
Q

When R is a phenyl(aryl) group, the structure represents a __________

A

aromatic carboxylic acid

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5
Q

carboxylic acids containing two carboxyl groups in their structure are called ______________

A

dixarboxylic acid

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6
Q

carboxylic acids that contain three carboxyl groups in their stucture are called ____________

A

tricarboxylic acids

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7
Q

those with an even number of carbon atoms ranging from 4 to 22 carbon atoms are referred to as _______________.

A

fatty acids

they are obtained by the hydroysis of animal and vegetable fats and oils

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8
Q

what is the structure of formic acid and its latin source of name?

A

HCOOH from latin name formica meaning ant

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9
Q

what is the structure of acetic acid and it latin name source?

A

CH3-COOH from latin name acetum meaning vinegar

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10
Q

what is the structure of propionic acid and it’s greek name source?

A

CH3 – CH2 – COOH from greek name propion meaning milk

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11
Q

what is the structure of butryic acid and it’s name source?

A

CH3– CH2 – CH2 – COOH from latin name butryum meaning butter

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12
Q

what is the structure of caprioic acid and it’s name source?

A

CH3 – CH2 – CH2 – CH2 – COOH from the latin word caper meaning goat

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13
Q

the position of the side chains or substitutes are indicated by ____________.

A

Greek letters

, α, β, γ, δ… for designating the 1st, 2nd, 3rd,…

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14
Q

Structure of oxalic acid

A

HOOC–COOH

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15
Q

Structure of malonic acid

A

HOOC–CH2–COOH

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16
Q

structure of succinic acid

A

HOOC–CH2–CH2–COOH

17
Q

Structure of glutaric acid

A

HOOC–CH2–CH2–CH2–COOH

18
Q

Structure of Adipic acid

A

HOOC–CH2–CH2–CH2–CH2–COOH

19
Q

Structure of Pimelic acid

A

HOOC–CH2–CH2–CH2–CH2–CH2–COOH

20
Q

Compounds which have a carboxyl group directly attached to an aromatic ring are classified
as

A

aromatic carboxylic acids

21
Q

The simplest aromatic carboxylic acid has a carboxyl group
attached to benzene ring and its common name is

A

benzoic acid

22
Q

According to IPUAC system, monocarboxylic acids are named as

A

alkanoic acids

23
Q

the name for monocarboxylic acid is derived from the corresponding alkane by replacing the suffix ‘‘–e’’ with________

A

> -oic acid

24
Q

In IUPAC system, dicarboxylic acids are named as .

A

alkanedioic acids

25
Q

These names for dicarboxylic acids are obtained by replacing the suffix ‘‘–e’’ in the name of corresponding alkane by ________________

A

‘‘–dioic
acid’’

26
Q

According to IUPAC system, aromatic carboxylic acids are named as

A

benzenecarboxylic acids

27
Q

The position of the substitutes in benzioic acid is indicated by the

A

Arabic numerals 1, 2, 3,..

28
Q

The lower aliphatic acids containing up to 9 carbon atoms are _________.

A

liquids

29
Q

State the color

Benzoic acid and most of its derivatives are also
____________ solids

A

colourless

30
Q

Describe the odor of methanoic and ethanoic acids

A

sharp irritating odour

31
Q

describe the odor of butanoic, pentanoic and hexanoic acids.

A

distinctly unpleasant odor

32
Q

Why do the higher acids have little odor?

A

Because they have lower volatility

33
Q

True of false

carboxylic acids have lower boiling points than alcohols of similar size.

A

False.

they have higher boiling poits due to the hydrogen bonding