Chemical Industry Flashcards

1
Q

Who established the conditions under which nitrogen, N2(g) and
hydrogen, H2(g), would combine to give ammonia?

A

Fritz Haber

IN 1909

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1
Q

Who established the conditions under which nitrogen, N2(g) and
hydrogen, H2(g), would combine to give ammonia?

A

Fritz Haber

IN 1909

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1
Q

Who established the conditions under which nitrogen, N2(g) and
hydrogen, H2(g), would combine to give ammonia?

A

Fritz Haber

IN 1909

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2
Q

Who established the conditions under which nitrogen, N2(g) and
hydrogen, H2(g), would combine to give ammonia?

A

Fritz Haber

IN 1909

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2
Q

Who established the conditions under which nitrogen, N2(g) and
hydrogen, H2(g), would combine to give ammonia?

A

Fritz Haber

IN 1909

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2
Q

Who established the conditions under which nitrogen, N2(g) and
hydrogen, H2(g), would combine to give ammonia?

A

Fritz Haber

IN 1909

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2
Q

Who established the conditions under which nitrogen, N2(g) and
hydrogen, H2(g), would combine to give ammonia?

A

Fritz Haber

IN 1909

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2
Q

Who established the conditions under which nitrogen, N2(g) and
hydrogen, H2(g), would combine to give ammonia?

A

Fritz Haber

IN 1909

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3
Q

Who established the conditions under which nitrogen, N2(g) and
hydrogen, H2(g), would combine to give ammonia?

A

Fritz Haber

IN 1909

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3
Q

Who established the conditions under which nitrogen, N2(g) and
hydrogen, H2(g), would combine to give ammonia?

A

Fritz Haber

IN 1909

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4
Q

Who established the conditions under which nitrogen, N2(g) and
hydrogen, H2(g), would combine to give ammonia?

A

Fritz Haber

IN 1909

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5
Q

the process produces ammonia with yiel of approximately _______%

A

10-20

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6
Q

The Haber synthesis was developed into an industrial process by ______________

A

Carl Bosch

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7
Q

is the Haber synthesis endothermic or exothermic? How much energy does it gain/release?

A

It is an exothermc reaction releasing 92.4 kj/mol

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8
Q

Choose the right one

Increasing the pressure causes the equilibrium to move in the forward/reverse direction

A

Forward

If we increase the pressure, we get more yield

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9
Q

Choose the right one

Increasng the temperature causes the equililbrium to move in the forward/reverse direction.

A

reverse

Decreasing temp causes to move in the forward direction

10
Q

What is the catalyst for the haber process?

A

Iron

11
Q

Fill the blanks

By using a pressure of around _______ atm and a temperature of about ________ degree celcius, the yield of ammonia is 10-20%

A

200 and 500

12
Q

True or False

During the industrial production of ammonia, the reaction never reaches equilibrium

A

True

the gas mixture leaving the reactor is cooled to remove the ammonia

13
Q

what is done with the heat released by the reaction?

A

It is removed and use to heat the incoming gas mixture

14
Q

What happens to the remaining mixture of reactant gases?

A

they get recycled throught the reactor

15
Q

what is the process to make sulphuric acid?

A

Contact Process

16
Q

The manufacture of sulphuric acid by contact process involves the catalytic oxidation
of ________ to _________,

A

SO2 to SO3

17
Q

Write the steps of the contact process

A

(i) Solid sulphur, S(s), is burned in air to form sulphric dioxide gas, SO2;
(ii) The gases are mixed with more air then cleaned by electrostatic precipitation
(iii) The mixture of sulphur dioxide and air is heated to 450 °C and subjected to
a pressure of 101.3 - 202.6 kPa (1-2 atmospheres) in the presence of a
vanadium catalyst (vanadium (V) oxide) to produce sulphur trioxide, SO3
(iv) Any unreacted gases from the above reaction are recylced back into the
above reaction.
(v) Sulphur trioxide, SO3(g) is dissolved in 98 % (18 M) sulphuric acid, H2SO4,
to produce disulphuric acid or pyrosulpuric acid, also known as fuming
sulphuric acid or oleum, H2S2O7
very slow.
(vi) Water is added to the disulphuric acid, H2S2O7, to produce sulphuric acid,
H2SO4.
H2S2O7(l) + H2O(l) —→ 2H2SO4(l

page 295