Chemical Equilibrium Flashcards
Define dynamic and equilibrium
Dynamic: both forward and backward reactions are still occurring at the same time
Equilibrium: proportion of reactants and products are unchanging
What will a change in conditions cause
It will cause the equilibrium to shift to counteract that change
How does concentration affect the equilibrium
- Increase concentration of reactants will shift to RHS as it favours the forward reaction and also increases the yield
How does pressure affect the equilibrium
Increase in pressure causes equilibrium to shift to the side with fewer miles
How does temperature affect the equilibrium
Increase in temperature will favour endothermic
Decrease in temperature will favour exothermic
What are the conditions used in the haber process and why are they used
- 450 C- not higher as it decrease the yield and not lower as the reaction would be too slow
- 250 atm- not higher as its too expensive not lower as the equilibrium will shift to the side with fewer moles
- Iron catalyst- cheaper as it speeds up a reaction without being used up
- Removal of ammonia- equilibrium shifts to RHS to increase the yield
Describe the haber process
- Nitrogen from air and hydrogen from methane
- These are compressed at 250 atm
- They are then transferred into a reaction chamber with a iron catalyst and ammonia gas is formed in this reaction
- This then goes to a heat exchanger where the heat is recycled to the reaction chamber
- This then goes to a condenser where nitrogen, hydrogen and ammonia gas are recycled back to the reaction chamber
- The liquid ammonia then goes to a storage vessel
What is a reversible reaction
It’s where the products react to produce the original reactants ie. an equilibrium is reached