Chemical Equilibria Flashcards

1
Q

Dynamic equilibrium?

A

when forward and reverse reactions take place at the same rate and happen simultaneously

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2
Q

Chemical Equilibrium?

A

A dynamic equilibrium where the rate of the foreword reaction is equal to the rate of the reverse reaction

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3
Q

Reversible reaction

A

When the products can be converted back into the reactants

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4
Q

A closed system?

A

the system is isolated from its surrounding environment in such a way that there is no transfer Of mass into and out. of the system.

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5
Q

Open system?

A

one in which mass or energy can be transferred into or out of the system during a reaction

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6
Q

Le Chatelier’s Principle?

A

When the equilibrium of a closed system ls disturbed, the system will reinstate a new equilibrium that favours the reaction that opposes the disturbance

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7
Q

what does it mean if the forward reaction is favored?

A

rate of the forward reac is greater than the rate of the reverse reac → conC. of substances on the left will decrease and the conc. of substances on the right will increase

equilibrium shifts to the right

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8
Q

What does it mean if the reverse reaction favored?

A

rate of the reverse reaction is greater than the rate of the forward reac → conC. of substances on the right will decrease and the conc. of substances on the left will increase

equilibrium shifts to the left

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9
Q

Factors that affect equilibrium position ?

A

Concentration
teMp
pressure
catalyst

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10
Q

effect of changing concentration on equilibrium → discuss a change in corc. of products and reactants

A
discuss le chatelier and general
> change in concentration
> favoured reaction
> equilibrium direction
> all conc. Increase
> equil restored
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11
Q

effect of temp on eqUil ?

A

+ H value → endothermic
-H value → exothermic

  • reverse is opposite

increase temp → endohermic reaction favoured

decrease temp → exothermic reaction favoured

Will move to Stabilize new temp

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12
Q

Effect of pressure ON equilibrium

A

only affects gases

Increase pressure→Equil will move to side with lower number of moles

decrease pressure → Equil moves to side with most number of moles

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13
Q

Effect of catalyst on equilibrium?

A

Increase rate of reverse and forward reactions equally → doesnt affect equilibrium

Equilibrium owy headed sooner IF Catalyst added to a system not already in equilibrium.

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