Chem13 Flashcards
What does the pauli exclusion principle say
Will the spins of electrons in the same orbital be parallel or opposites
No two electrons in an atom have the same set of quantum numbers
Opposite
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Types of stereoisomers
Enantiomers and meso compounds
Constitutional and stereoisomers
When all chiral centers change, Theyre enantiomers if theres no symmetry and meso compound if there is symmetry, but if only some chiral center changes theyre distereomers
Sigma/pi bonds are stronger
Sigma/pi bonds are made of unhybridized orbitals
Sigma
Pi
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A dash between the hybridization of the atoms forming the bond
One
The number of bonds the atom makes in a Lewis structure
Tetrahedral
What elements are in the d block
What kind of bonds do unhybridized orbital form
What kind of bonds do hybridized orbital form
What is a paramagnetic element
Why is it more stable to have unpaired electrons
Transition metals
Atomic orbitals hybridized for molecules
Pi
Sigma
An element with unpaired electrons
Electrons repel
Define:
Radical
Carbene
Carbocation
Carbanion
Anything with at least one unpaired electron
A carbon with two bonds and a lone pair
A carbon with a positive formal charge
A carbocation with a lone pair
What do you add to a hydrocarbon name if it has an amide group
Whats an n-methyl
What do you call amides secondary or primary or tertiary based on
-amide
A methyl on a nitrogen atom
How many carbons are bonded to a nitrogen atom
Thermal energy vs temperature
What kind of kinetic energy is in a solid
What kind of kinetic energy is in a gas
Wuz heat
Ehat does a thing have to be to have thermal energy
Thermal is the sum kinetic energy of the particles but temperature is the average
Vibrational
Translational
The amount of thermal energy transferred
Be warmer than absolute zero