chem112exam1 Flashcards

1
Q

what is the def of a solution.

A

homogenous mixture of two or more substances.

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2
Q

what is the solvent in aqueous solutions? what is the solute?

A

water. Solute is a solid liquid or gas.

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3
Q

what is the def of solubility?

A

the amount of substance that will dissolve in a given amount of solvent.

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4
Q

what is true about two particles with opp. charges and their potiental energy?

A

Two particles with opp. charges (ex. proton and electron) move toward each other because their potential energy decreases as their seperation decreases.

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5
Q

what is entropy?

A

a measure of energy dispersal or energy randominzation. the tendency to mix is related to entropy.

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6
Q

what are the types of forces?

A

dipole-dipole, ion-dipole, hydrogen bond, dispersion.

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7
Q

energy tends to?

A

spread out or disperse when not restrained from doing so. the reason two ideal gases mix.

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8
Q

there are forces present between what in solution?

A

solute/solute, solvent/solvent, solute/solvent.

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9
Q

what forms if solvent/solute interactions > solvent/solvent and solute/solute

A

solution

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10
Q

what forms if solvent solute interactions are equal to solvent/solvent and solute/solute?

A

solution

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11
Q

what forms if solvent/solute interactions < solvent/solvent and solute/solute?

A

if its a small difference a solution will form if its a big difference solution will not form.

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12
Q

polar solvents tend to dissolve what?

A

polar and ionic solutes.

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13
Q

nonpolar solvents tend to dissolve what?

A

nonpolar solutes.

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14
Q

is methanol (CH3OH) more likely to be dissolvable in water or in a nonpolar solvent?

A

water. contains hydrogen bonding.

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15
Q

when hydrogen bonds occur what other two forces will also occur?

A

disperson, dipole-dipole

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16
Q

if a bond is ionic it is?

A

polar

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17
Q

what kind of bonds occur between ionic (polar) compounds?

A

ion-dipole, dispersion

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18
Q

what type of bonds occur between non polar covalent compounds?

A

dispersion.

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19
Q

polar covalent compounds without hydrogen bonding have what kind of bonds?

A

dispersion, dipole dipole

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20
Q

what is the def of a saturated solution?

A

a solution in which the dissolved solute is in equilibrium with the undissolved solid

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21
Q

solubility of a substance?

A

how much it can dissolve before a solution becomes saturated. solubility increases with increasing temperature.

one factor is:
1. temp

22
Q

the soubility of a gas in liquid?

A

decreases with increasing temperature

23
Q

soubility _____ with increasing pressure and _____ with decreasing pressure?

A

increases, decreases

24
Q

a soultion is saturated with both a solid and a gas at 85 degree C what will happen if the solution is cooled to 5 degree C

A

some solid will precipitate out of the solution, becuase the solbility of a solid decreases when temperature decreases.

25
what is molarity
moles solute/liters solution
26
what is a pure covalent bond
electrons are shared equally between the two atoms
27
what is a polar covalent bond?
a chemical bond in which the bonding electrons are unevenly shared.
28
electronegitivity increases as you go the right and up. floruine is the most electronegitive, francium is the least electronnegitive.
29
breaking bonds _____ energy and is therefore _____ (pos or neg).
absorbs, positive. The bonds broken from the reactant in the product side is positive.
30
is breaking bonds endo or exothermic and why?
endothermic. energy is adsorbed to break bonds.
31
forming bonds is endothermic or exothermic?
exothermic. releases energy.
32
forming bonds ___ energy and is therefore _____ (pos or neg)
releases, neg. the amount of bonds formed in the product side is negitive.
33
what increases with increasing molar mass as long as other factors remain constant?
Boiling point.
34
what is the dipole dipole force
the positive end of one force is attracted to the neg. end of another force.
35
dipole dipole forces occur in all polar molecules and usually have a higher _____ and _____ point than non polar molecules with the same _____ _____
boiling and melting. molar mass.
36
hydrogen bonds (intermolecular forces) are present in all ___ molecules that contain H bond directly to __, ___, or __.
polar. F,N,O.
37
hydrogen bonds increase the what within a molecule?
melting and boiling point realitive to others with simular molar mass.
38
what is the transition from liquid to gas?
vaporization.
39
what is the transition from gas to liquid called?
condensation.
40
rate of vaporization usually increases with?
- increasing temp -increasing surface area - decreasing strength of intermolecular forces
41
rate the vaporiztion is equal to?
the pressure of gas in dynamic equalibrium with its vapor pressure.
42
colligitive properties depend on what?
the number of particles dissolved in a soultion.
43
what are the colligitive properties?
1. vapor pressure lowering 2. freezing point depression 3. boiling point elevation 3. osomotic pressure
44
what is osomotic flow and pressure?
Osmotic flow: flow of a solvent from a solution of lower solute concentration to higher solute concentration. Osmotic pressure: the pressure required to stop osmotic flow.
45
what is true about a strong electrolye solution?
an electrolye solution produces more of an effect on collgitive properties than a non electrolye solution of the same molar concentration.
46
strong electrolyes _____ in solution to produce a greater number of ______ particles
dissociate. dissolved.
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