chem112exam1 Flashcards

1
Q

what is the def of a solution.

A

homogenous mixture of two or more substances.

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2
Q

what is the solvent in aqueous solutions? what is the solute?

A

water. Solute is a solid liquid or gas.

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3
Q

what is the def of solubility?

A

the amount of substance that will dissolve in a given amount of solvent.

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4
Q

what is true about two particles with opp. charges and their potiental energy?

A

Two particles with opp. charges (ex. proton and electron) move toward each other because their potential energy decreases as their seperation decreases.

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5
Q

what is entropy?

A

a measure of energy dispersal or energy randominzation. the tendency to mix is related to entropy.

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6
Q

what are the types of forces?

A

dipole-dipole, ion-dipole, hydrogen bond, dispersion.

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7
Q

energy tends to?

A

spread out or disperse when not restrained from doing so. the reason two ideal gases mix.

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8
Q

there are forces present between what in solution?

A

solute/solute, solvent/solvent, solute/solvent.

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9
Q

what forms if solvent/solute interactions > solvent/solvent and solute/solute

A

solution

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10
Q

what forms if solvent solute interactions are equal to solvent/solvent and solute/solute?

A

solution

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11
Q

what forms if solvent/solute interactions < solvent/solvent and solute/solute?

A

if its a small difference a solution will form if its a big difference solution will not form.

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12
Q

polar solvents tend to dissolve what?

A

polar and ionic solutes.

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13
Q

nonpolar solvents tend to dissolve what?

A

nonpolar solutes.

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14
Q

is methanol (CH3OH) more likely to be dissolvable in water or in a nonpolar solvent?

A

water. contains hydrogen bonding.

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15
Q

when hydrogen bonds occur what other two forces will also occur?

A

disperson, dipole-dipole

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16
Q

if a bond is ionic it is?

A

polar

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17
Q

what kind of bonds occur between ionic (polar) compounds?

A

ion-dipole, dispersion

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18
Q

what type of bonds occur between non polar covalent compounds?

A

dispersion.

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19
Q

polar covalent compounds without hydrogen bonding have what kind of bonds?

A

dispersion, dipole dipole

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20
Q

what is the def of a saturated solution?

A

a solution in which the dissolved solute is in equilibrium with the undissolved solid

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21
Q

solubility of a substance?

A

how much it can dissolve before a solution becomes saturated. solubility increases with increasing temperature.

one factor is:
1. temp

22
Q

the soubility of a gas in liquid?

A

decreases with increasing temperature

23
Q

soubility _____ with increasing pressure and _____ with decreasing pressure?

A

increases, decreases

24
Q

a soultion is saturated with both a solid and a gas at 85 degree C what will happen if the solution is cooled to 5 degree C

A

some solid will precipitate out of the solution, becuase the solbility of a solid decreases when temperature decreases.

25
Q

what is molarity

A

moles solute/liters solution

26
Q

what is a pure covalent bond

A

electrons are shared equally between the two atoms

27
Q

what is a polar covalent bond?

A

a chemical bond in which the bonding electrons are unevenly shared.

28
Q

electronegitivity increases as you go the right and up. floruine is the most electronegitive, francium is the least electronnegitive.

A
29
Q

breaking bonds _____ energy and is therefore _____ (pos or neg).

A

absorbs, positive. The bonds broken from the reactant in the product side is positive.

30
Q

is breaking bonds endo or exothermic and why?

A

endothermic. energy is adsorbed to break bonds.

31
Q

forming bonds is endothermic or exothermic?

A

exothermic. releases energy.

32
Q

forming bonds ___ energy and is therefore _____ (pos or neg)

A

releases, neg. the amount of bonds formed in the product side is negitive.

33
Q

what increases with increasing molar mass as long as other factors remain constant?

A

Boiling point.

34
Q

what is the dipole dipole force

A

the positive end of one force is attracted to the neg. end of another force.

35
Q

dipole dipole forces occur in all polar molecules and usually have a higher _____ and _____ point than non polar molecules with the same _____ _____

A

boiling and melting. molar mass.

36
Q

hydrogen bonds (intermolecular forces) are present in all ___ molecules that contain H bond directly to __, ___, or __.

A

polar. F,N,O.

37
Q

hydrogen bonds increase the what within a molecule?

A

melting and boiling point realitive to others with simular molar mass.

38
Q

what is the transition from liquid to gas?

A

vaporization.

39
Q

what is the transition from gas to liquid called?

A

condensation.

40
Q

rate of vaporization usually increases with?

A
  • increasing temp
    -increasing surface area
  • decreasing strength of intermolecular forces
41
Q

rate the vaporiztion is equal to?

A

the pressure of gas in dynamic equalibrium with its vapor pressure.

42
Q

colligitive properties depend on what?

A

the number of particles dissolved in a soultion.

43
Q

what are the colligitive properties?

A
  1. vapor pressure lowering
  2. freezing point depression
  3. boiling point elevation
  4. osomotic pressure
44
Q

what is osomotic flow and pressure?

A

Osmotic flow: flow of a solvent from a solution of lower solute concentration to higher solute concentration.
Osmotic pressure: the pressure required to stop osmotic flow.

45
Q

what is true about a strong electrolye solution?

A

an electrolye solution produces more of an effect on collgitive properties than a non electrolye solution of the same molar concentration.

46
Q

strong electrolyes _____ in solution to produce a greater number of ______ particles

A

dissociate. dissolved.

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47
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48
Q
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