chem 2 test 1 Flashcards

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1
Q

primary alcohol

A

2 H’s

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2
Q

Secoundary Alcohols

A

1 H’s

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3
Q

Tertiary alcohols

A

no H’s

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4
Q

organic compound

A

composed of carbon and hydrogen

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5
Q

Geometric isomers/cis-trans isomers

A

same connectivity but different spatial arrangements

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6
Q

Oxidation reaction (o)

A

single bound OH to double bonded O

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7
Q

dehydration reaction (H+/triangle) or (H2SO4/heat)

A

alcohol (OH) to alkenes (Double bonded)

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8
Q

Alkanes

A

single bonded molecules

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9
Q

molecular geometry of alkanes

A

tetrahedral 109.5

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10
Q

isobutyl

A

chain of three with a methyl on two

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11
Q

secbutyl

A

chain of four, connected on two

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12
Q

tert-butyl

A

cross/X

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13
Q

boiling/melting point for alkanes

A

as number of carbons increase, boiling point increases

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14
Q

boiling/melting point for branching alkanes

A

as the number of branches increase boiling point decreases

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15
Q

combustion of alkanes

A

alkane +O2 = Co2+h20

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16
Q

alkenes

A

double bond

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17
Q

alkynes

A

triple bond

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18
Q

Hydrogenation (H2/Pt,Ni, or Pd)

A

Alkene to alkane (double to single) or alkyne (+2H2) to alkane (triple to single)

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19
Q

hydration (+h-oh -> h2SO4) or (+h20 -> H)

A

alkene to alcohol

20
Q

toluene

A

benzene with methyl

21
Q

aniline

A

benzene with NH2

22
Q

phenol

A

benzene with OH

23
Q

ortho/o

A

common naming for two apart on benzene

24
Q

meta/m

A

common naming for 3 apart on benzene

25
Q

Para/p

A

common naming for 4 apart on benzene

26
Q

alcohol with 2 OH groups

A

diol

27
Q

Thiols

A

SH group

28
Q

ethers

A

C-O-C

29
Q

alcohols vs ethers boiling point

A

alcohols have greater boiling point

30
Q

major product

A

less amount of H on double bond

31
Q

formaldehyde

A

OH-CH3

32
Q

Aldehyde

A

o=c to one H and one C

33
Q

Ketone

A

0=c bonded to two C

34
Q

acetaldehyde (ethanal)

A

0=c bonded to CH3 and H

35
Q

Tollen’s test (aldehyde + 2Ag ->o)

A

H becomes OH

36
Q

Benedict’s test (aldehyde+ 2Cu->)

A

H becomes OH

37
Q

reduction of Ketones and aldehydes (->pd, pt, or pd)

A

double bond O breaks to become OH and another H is added

38
Q

Hemiacetals

A

HO-C-C

39
Q

Acetals

A

C-O-C-C

40
Q

Aldose

A

contain h-c=O group on end of carbon backbone

41
Q

Ketose

A

contains c=0 on side of carbon backbone

42
Q

chiral molecules

A

same molecular formula but differnt bonding aragements

43
Q

stereoisomers

A

identical molecular formula bot arranged differently in space

44
Q

chiral

A

nonsuperimposable mirror images

45
Q

achiral

A

superimposable

46
Q

L-Isomer

A

OH on left

47
Q

D-Isomer

A

OH on right