chapters 3 and 4 Flashcards
ionic bonding
the complete transfer of valence electrons
covalent bonding
sharing of electrons
polar bonds
unequal sharing of electrons
general trend of electronegativity
increases going left to right and up a column
VSEPR theory
structures surrounding and atom is determined by minimizing electron pair repulsions
chemical bond
force that holds atoms together
bond energy
required energy to break a bond
bond length
distance where energy is minimal
nonmetallic elements achieve a noble gas configuration by _____ electrons
sharing
metals are _____
cations
nonmetals are _____
anions
cation is generally _____ than parent atom
smaller
anions are generally _____ than parent atom
larger
ion size______ going down a group
increases
ions generally adapt ______ configurations in ionic compounds
noble gas electron
isoelectronic ions
ions containing the same number of electrons
______ protons means ______ attraction and _______ ions
more, greater, smaller
electronegativity
ability of an electron to attract shared electrons to itself
lattice energy
change in energy that takes place when separated gaseous ions are packed together to form an ionic solid
all compounds with _____% or more ionic character are considered to be ionic solids
50
delocalization of electrons
eletrons free to move through entire molecule
as number of shared electrons _____ bond length _____
increases, shortens
energy terms with bond breaking have a ____ sign
positive
energy terms with bond making have a ___ sign
negative
list the exceptions to the octet rule
boron, and any row 3 or lower
resonance
when more than one correct lewis structure can be drawn
formal charge formula
valence-non bonding-bonding/2
valence electron formula
lone pairs+ 1/2(shared electrons)
how to name type 1 compounds
cation first anion 2nd
cation takes name from element
anion named by taking root of element name and adding -ide
how to name type 2 compounds
same as type one
cation first then anion
must specify the charge
add -ide to the end
how to name type 3 compounds
first element named with full name
2nd element named like anion
prefixes for the nunber of atoms
mono prefix not used for first element
molecular structure
3d arrangement of atoms in a molecule
2 pairs of electrons means what shape
linear
3 pairs of electrons means what shape
trigonal planar
4 pairs of electrons means what shape
tetrahedral
5 pairs of electrons means what shape
trigonal bipyramidal
6 pairs of electrons means what shape
octahedral
true or false in vsper a double bond is counted as one effective pair
true
dipole moment
molecule with a center of positive and negative charge
electrostatic potential diagram
colors of visible light are used to show the variation in charge distribution
red= electron rich
blue= electron poor
hybridization
mixing of native atomic orbitals to form special orbitals for bonding
sigma bond
electron pair is shared in an area centered on a line running in between the atoms
pi bond
parallel p orbitals that occupy space above and belowine joining atoms
in a single bond how many sigma bonds are there
1
in a double bond there is ____ sigma and ____pi
1 and 1
in a triple bond there is ____ sigma and ___pi
1 and 2
bond order
(bonding electons-antibonding electrons)/2
_____ bond order means ____bond strength
larger, greater
paramagnetic
unpaired electrons make something paramagnetic
diamagnetic
when all electrons are paired
as bond order _____ bond energy _____ and bond length _____
increases, increases, decreases
is o2 paramagnetic or diamagnetic
paramagnetic
electron geometry
includes lone pairs and bonding electrons
molecular geometry
includes only bonding pairs
nonpolar
if molecule has a symmetric shape and like bonds
formal for change in E
change in E=bonds broken-bonds formed
ionic bonds generally form between what
metals and nonmetals
to choose best lewis structure using formal charge the charge of the central atoms should be close to ____
zero
what shape has sp hybridization
linear
what shapes have sp2 hybridization
bent and trigonal planar
what shapes have sp3 hybridization
tetrahedral, seesaw, trigonal pyramidal
what shapes have sp3d hybridization
trigonal bipyramidal
what shape has sp3d2 hybridization
octahedral
ammonium
NH4+
carbonate
CO3^2-
chlorate
ClO3-
chromate
CrO4^2-
cyanide
CN-
hydroxide
OH-
nitrate
NO3-
phosphate
PO4^3-
sulfate
SO4^2-
permanganate
MnO4-
type 2 compounds typically involve….
transition metals
type 3 compounds are made of…
two nonmetals
type 1 compounds always have…
a cation and anion
single bond has a bond order of
1
double bond has a bond order of 2
triple bond has a bond order of 3