Chapters 20 and 21 Flashcards
Oxidized
loses electrons (reducing agent)
Reduced
gains electrons (oxidizing agent)
Anode (electrolytic)
oxidation, positive electrode
Cathode (electrolytic)
reduction, negative electrode
Where ions move through in voltaic cells
move through the salt bridge, negative ions move to positive electrode and positive ions move to negative electrodes
Where electrons move through in voltaic cells
move through the wire
Voltaic cell description
spontaneous oxidation-reduction reaction
Voltaic cells
produce energy
Electrolytic cells
absorb energy
Electrolysis
process of electrolytic cell
Rules for assigning oxidation numbers
oxidation number of monatomic ions are equal to ionic charge
hydrogen in a compound is +1, except in metal hydrides it’s -1
oxygen in a compound is -2
oxidation numbers of uncombined atoms are 0
neutral compounds’ oxidation number’s sum must equal 0
the sum of oxidation numbers in a polyatomic ion must equal the ionic charge of the ion
Steps for balancing a redox reaction
assign oxidation numbers
identify which atoms were oxidized/reduced
connect atoms that undergo oxidation and undergo reduction with bracket lines
make total increase in oxidation number equal to the total decrease in oxidation number by using appropriate coefficients
Difference between dry voltaic cells and wet voltaic cells
wet cells have a liquid electrolyte while dry cells have a paste electrolyte
Main difference between voltaic and electrolytic
electrolytic - electrons are pushed by outside source
voltaic - electrons move because of spontaneous redox reaction
Anode (voltaic)
negative, oxidizing