Chapters 1-4 Flashcards
Cohesion
- Water molecules stick together due to hydrogen bonding
- Helpful when fighting gravity to transport water through plants
Adhesion
- Water molecules being attracted to the cell walls in things such as plants
- Helpful when fighting gravity to transport water through plants
Surface Tension
- Water molecules are hydrogen bonded to each other, but not the air above
- Makes it very difficult to stretch or break water droplets
Moderation of Temperature by Water
-Absorbing heat from air that is warmer, releasing the stored heat into air that is cooler
Temperature
-AVERAGE KE of molecules in a body of matter, independent of volume
Thermal Energy
- KE associated w/ random movement of atoms or molecules
- Total kinetic energy, dependent on volume
- When transferred from one body of matter to another= heat
Calorie
- cal
- The amount of heat necessary to raise the temperature of 1 g of water 1 degree C
Kilocalorie
- 1,000 calories
- Quantity of heat required to raise 1 kg of water by 1 degree C
Water’s High Specific Heat
- Water’s specific heat= 1 Calorie
- Water’s high specific heat makes it change temperature less than other substances
- Traced back to hydrogen bonds
- Heat absorbed= hydrogen bonds break
- Heat lost= hydrogen bonds form
Specific Heat
- How well a substance resists changing its temp when it absorbs or releases heat
- The amount of heat that must be absorbed or lost for 1g of that substance to change its temp by 1 degree C
Evaporative Cooling
- As a liquid evaporates, the surface of that liquid that remains cools down
- Happens because the molecules w/ the greatest KE leave (hottest ones)
Heat of Vaporization
-The quantity of heat a liquid must absorb for 1 g of it to be converted from a liquid to a gaseous state
Emergent Properties of Water
- Moderation of Temperature
- Cohesion
- Floating Ice on Liquid Water
- Water as a solvent for life
Floating Ice on Liquid Water
- Ice (solid)= less dense than its liquid form, water
- Water molecules expand instead of contracting when frozen
- Water freezes because molecules are moving too slowly to break hydrogen bonds
Water as a Solvent
- Water= a good solvent because of hydrogen bonds
- Ex: When dissolving salt, hydrogen cations are attracted to chloride anions and oxygen anions are attracted to sodium cations
Solution
-A liquid that is a completely homogeneous mixture of two or more substances
Solvent
- The dissolving agent of a solution
- Ex: water
Solute
-The substance that is dissolving
Aqueous Solution
-Solution where solvent= water
Hydration Shell
-The sphere of water molecules around each dissolved ion
Hydrophilic Substances
-Any substance that likes water, will SOMETIMES dissolve
Hydrophobic Substances
- Nonionic/nonpolar substances (can’t create hydrogen bonds), repel water
- Ex: Vegetable oil
Molecular Mass
-The sum of all the masses of the atoms in a molecule
Mole (mol)
- 6.02x10^23
- Avagadro’s number
- 1 mole= 1 dalton
Molarity
-The number of moles of solute per liter of solution
Equation: A x B= C x D
When a water molecule loses a proton/ hydrogen ion, what happens?
- A hydroxide ion is made (OH-)
- OH- is basic
What happens when a water molecule gains an extra proton/hydrogen ion?
- Hydronium ion (H3O+) is made
- Also known simply as H+, acidic
PH scale
-Less than 7= acidic
-More than 7= basic
=7 is neutral
-Ex: Water
Organic Chemistry
- The study of carbon compounds
- Range from simple to complex
Abiotic Synthesis
- Organic compounds arising from nonliving things
- Thought to be an early stage in the origins of life
- Demonstrated by Stanley Miller and Harold Ureg’s experiments
Spontaneous Generation
-Living organisms come from non-living organisms
Ex: Maggots from meat, come from rotten meat, but really came from flies
Carbon’s Emergent Properties
- Can form diverse molecules by bonding to four other atoms
- Due to carbon’s four valence electrons, creates single or double covalent bonds
- Simple or large, complex moleculed
- Variation in carbon skeletons is one important source of molecular complexity and diversity that characterizes living matter
Hydrocarbons
- Organic molecules consisting of only hydrogen and carbon
- Hydrophobic
- Undergo reactions that release a relatively large amount of energy
Isomers
- Compounds that have the same number of atoms of the same elements, but different structures
- Leads to different properties
- 3 Types: Structural, cis-trans, enantiomers
Structural Isomers
- Differ in the covalent arrangements of their atoms
- May also differ in the location of their double bonds
Cis-Trans Isomers
- Carbons have covalent bonds to the same atoms, but atoms differ in spatial arrangements due to double bonded carbons
- Cis= same side of DB
- Trans= opposite side DB
Enantiomers
- Isomers that are mirror images of each other due to asymmetrical carbon
- Left handed vs right handed version of molecule
Functional Groups
- Chemical groups involved directly in chemical reactions
- Each has certain properties such as shape and charge, which cause it to participate in chemical reactions in a characteristic way
- 7 groups:
- Hydroxyl
- Carbonyl
- Carboxyl
- Amino
- Phosphate
- Methyl
- Sulfhydrl
Hydroxyl
- Written (-OH)
- Polar due to electronegative oxygen
- Forms hydrogen bonds with water
- Compound name: alcohol
Carbonyl
- Written (C=O)
- Sugars with ketone groups called ketoses
- Those with aldehydes are called aldoses
- Compound name: Ketone or aldehyde