Chapter 9 Enthalpy Flashcards

1
Q

What is enthalpy?

A

A measurement of the heat energy in a chemical system

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2
Q

What does the law of conservation of energy state?

A

Energy can neither be created nor destroyed

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3
Q

What is the energy transfer in an exothermic reaction?

A

From the system to the surrroudings

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4
Q

What is the energy transfer in an endothermic reaction?

A

From the surroundings to the system

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5
Q

What is activation energy?

A

The minimum energy required for a reaction to take place

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6
Q

What are standard conditions?

A

100kPa pressure

298k Temperautre

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7
Q

What is standard enthalpy change of reaction?

A

The enthalpy change when the reaction occurs in the molar quantites shown in the chemical equation, under standard conditions

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8
Q

What is standard enthalpy change of formation?

A

The enthalpy change when 1 mole of a compound is formed from its elements in their standard sates

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9
Q

What is standard enthalpy change of combustion?

A

The enthalpy change when 1 mole of a substance is completely burned in oxygen

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10
Q

What is standard enthalpy change of neutralisation?

A

The enthalpy change when an acid and an alkali react together under standard conditions, to form 1 mole of water

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11
Q

What is specific heat capacity?

A

The energy required to raise the temperature of 1g of a substance by 1K

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12
Q

What is water’s specific heat capacity?

A

4.18 J/g/K

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13
Q

What is the equation for energy change (Q)?

A

Q = mc(Delta)T
m = Mass
c = specific heat capacity
Delta T = Change in temp

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14
Q

What are some possilbe reasons why the experimental value of enthalpy change is not completely accurate?

A
  • heat lost to the surroundings
  • Incomplete combustion of X
  • Evaporation of X from the wick
  • Non-standard conditions
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15
Q

What is average bond enthalpy?

A

The energy required to break one mole of a specified type of bond in a gaseous molecule

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16
Q

What is the word equation for enthalpy change of combustion?

A

Enthalpy change = Sum of bond enthalpies in reactants - Sum of bond enthalpies in products

17
Q

For reactants, what is the standard enthalpy change of formation?

A

0

18
Q

What is the word equation for enthalpy change of formation?

A

Enthalpy change = Sum of bond enthalpies in products- Sum of bond enthalpies in reactants