Chapter 9 Flashcards
complex coordination ion
molecule with cation bonded to at least on electron pair donor
coordinate covalent
electron pair donor (lewis base) and acceptor (acid) form stable lewis acid- base adducts
forms complex ions
percent composition by mass
mass of solute/ mass of solution x100%
mole fraction equation
Xa= moles A / total moles
molarity
moles of solute/ liters solution
molality
moles solute/ kg solvent
normality
equiv. of interest/ liter
dilution
MiVi= MfVf
molarity and volume
solubility product constant
Ksp= [An+]^m [Bm-]^n
AT SATURATION
when AmBn -> mAn+ + nBM-
no pure solids or liquids
ion product
shows if at saturation when compared to ksp
IP= [An+]^m [Bm-]^n
comparing Ip and Ksp
Ip< Ksp= unsaturated, solute will continue to disolve
Ip> Ksp= supersaturated, precipitation will occur
common ion effect
reduce solubility of a compound when constitute ion is in solution
colligative properties
depends on concentration of dissolved particles
VP depression, BP elevation, FP depression and osmotic pressure
Raoults Law
accounts for VP depression caused by solutes in solution
as concentration increases, VP decreases- because solution blocks evap
Raoults Law equation
Pa= Xa Pa0
p= pressure of solvent and solute
Pa0= pure vapor pressure of solvent