Chapter 1 Flashcards

1
Q

Atomic number

A

Z, number of protons

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2
Q

Mass number

A

A, sum of protons and neutrons

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3
Q

isotopes

A

same atomic number, different masses (different number of neutrons)

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4
Q

atomic mass

A

equal to mass number in amu

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5
Q

atomic weight

A

weighted average of isotopes

mass of 1 mole in grams

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6
Q

avadagros number

A

1 mole, number of things

6.022 x 10 ^23

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7
Q

Rutherford

A

atoms have dense, positive nucleus

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8
Q

quanta

A

bundles of energy emitted as electromagnetic radiation from matter

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9
Q

energy of quanta equation

A

E= hf

h is constant= 6.626 x 10^ -34

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10
Q

Bohr

A

atoms is central protons with electrons in orbit

force is electrostatics between protons and electrons

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11
Q

angular momentum equation

A

L= nH/2pi

n is principal quantum number

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12
Q

energy of electron equation

A

E= -RH/ n squared

R= 2.18 x 10^-18 J/e

energy increases farther out from nucleus

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13
Q

atomic emission energy

A

E= hc/ wavelength

c= 3x 10 ^8

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14
Q

line spectrum

A

emit fluorescence when moving from excited to ground

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15
Q

Energy level tansition

A

E= Hc/ wavelength
= Rh (1/ni^2 - 1/nf^2

energy emitted is energy difference between initial and final energy

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16
Q

absorption spectra

A

from exciting electrons at specific wavelength

17
Q

orbitals

A

electrons move rapidly around these regions of space

18
Q

heisenberg uncertainty principle

A

cant determine electron momentum and position together

19
Q

pauli exclusion

A

no 2 electrons can have same set of 4 quantum numbers

20
Q

quantum numbers

A

n, l, ml, ms

21
Q

principal quantum number

A

n, positive integer, larger means higher energy level and shell radius

22
Q

max electrons in shell

A

2n squared

23
Q

azimuthal quantum number

A

l, angular momentum, shape and number of subshells

from 0 to n-1

0=s 1=p 2=d 3=f

24
Q

max number of electrons in subshell

A

4l +2

25
Q

magnetic quantum number

A

ml, where electrons are likely found, orbital holds 2 electrons

from -l to l
s is sphere and p is dumbbell

26
Q

spin quantum number

A

ms, - or + 1/2

orbitals have paired spin

27
Q

configuration

A

pattern in which subshells are filled

first number is n

letter is subshell

superscript is number of electrons in subshell

28
Q

afbau principle

A

electrons fill low to high energy subshell and fill completely before next

29
Q

N+ L rule

A

shows rank of highest energy

30
Q

hunds rule

A

fill orbitals to have max number of half filled orbitals with parallel spin

if all have full- its lower E and stable

31
Q

exceptions to configurations

A

chromium has s1,d5

copper has s1 d10

32
Q

paramagnetic

A

magnetic field causes parallel spins in unpaired electrons, causes align and attraction to magnetic field

33
Q

diamagnetic

A

only paired electrons, slightly repelled by magnetic field