chapter 8 + 9 vocab Flashcards

1
Q

linear bond angle

A

180

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2
Q

tetrahedral bond angle

A

109.5

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3
Q

trigonal bipyramindal angle

A

90 and 120

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4
Q

what shape do you get when removing one atom from the vertex of a tetrahedron (lone pair)

A

trigonal pyramindal

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5
Q

what shape do you get when removing two atoms from the vertex of a tetrahedron (2 lone pairs)

A

bent shape

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6
Q

bent shape bond angle

A

104.5

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7
Q

trigonal pyramidal bond angle

A

107

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8
Q

lattice energy

A

the energy required to separate 1 mole of an ionic compound into its gaseous ions. A large, positive lattice energy indicates a strong attraction

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9
Q

sp-hybrizadation

A

orbitals on the central atom mix to form hybrid orbitals
number of hybrid orbitals=number of orbitals that are mixed
hybrid number= 1 less than e- domains

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10
Q

sp- hybridization shape

A

linear (or bent)

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11
Q

sp^2-hybridization shape

A

trigonal planar

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12
Q

sp^3-hybridization shape

A

tetrahedral

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13
Q

electronegativity difference

A

shared e- shift to more electronegative element

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14
Q

electronegativity across a period

A

increases

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15
Q

electro.neg. down a group

A

decreases

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16
Q

resonance

A

all bonds are equivalent in length and energy. (double bonds can be on any side)

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17
Q

ionic bond`

A

when cation and anion bond creating a rigid well defined 3 dimensional arrangement

18
Q

cations

19
Q

anions

20
Q

covalent bond

A

formed by 2 atoms by sharing one or more pairs of e-

21
Q

polar

A

one atom exerts a greater attraction for the bonding electrons than the other

22
Q

nonpolar

A

electrons shared eqully

23
Q

double and triple bonds

A

as # of bonds increase, bond strength increases, length decreases

24
Q

INTRAmolecular bonding

A

bonds between atoms or ions that create new compounds. e- are transfered or shared between atoms

25
INTERmolecular bonding
attractions between molecules due to dipoles on the molecules or shifting e- clouds (melting point, boiling p. state @ room temp)
26
bond energy
the potential energy at the most stable point (shorter bonds are stronger than longer ones, values are neg.)
27
bond polarity
measure of how equally or unequally the electrons in a covalent bond are shared
28
electron-domain
bonds around central atom
29
non bonding domain
lone pairs (not part of e- domains geometry)
30
bonding domain
bond between atoms
31
2 e- domains
linear e- domain gemoetry
32
3 e- domains
trigonal planar domain gemonetry
33
trigonal planar bond angle
120
34
4 e- domains
tetrahedral domain geom
35
5 e- domains
trigonal bipyramidal domain geom
36
6 e- domains
octahedral domain geom
37
formal charge
the charge an atom would have if each bonding e- pair between the atoms in a molecule were equally shared between its two atoms
38
best structure formal charge
when negative charge is on most electronegative strucure
39
molecular geometry
shape based off of e-domain gemonetry including lone pairs
40
e- domains gemetry
shape based of bonding domains
41
vesper theory
how different e- domains determine molecular geometry
42
lewis dot structure
the octet rule