chapter 8 + 9 vocab Flashcards
linear bond angle
180
tetrahedral bond angle
109.5
trigonal bipyramindal angle
90 and 120
what shape do you get when removing one atom from the vertex of a tetrahedron (lone pair)
trigonal pyramindal
what shape do you get when removing two atoms from the vertex of a tetrahedron (2 lone pairs)
bent shape
bent shape bond angle
104.5
trigonal pyramidal bond angle
107
lattice energy
the energy required to separate 1 mole of an ionic compound into its gaseous ions. A large, positive lattice energy indicates a strong attraction
sp-hybrizadation
orbitals on the central atom mix to form hybrid orbitals
number of hybrid orbitals=number of orbitals that are mixed
hybrid number= 1 less than e- domains
sp- hybridization shape
linear (or bent)
sp^2-hybridization shape
trigonal planar
sp^3-hybridization shape
tetrahedral
electronegativity difference
shared e- shift to more electronegative element
electronegativity across a period
increases
electro.neg. down a group
decreases
resonance
all bonds are equivalent in length and energy. (double bonds can be on any side)
ionic bond`
when cation and anion bond creating a rigid well defined 3 dimensional arrangement
cations
metals
anions
nonmetals
covalent bond
formed by 2 atoms by sharing one or more pairs of e-
polar
one atom exerts a greater attraction for the bonding electrons than the other
nonpolar
electrons shared eqully
double and triple bonds
as # of bonds increase, bond strength increases, length decreases
INTRAmolecular bonding
bonds between atoms or ions that create new compounds. e- are transfered or shared between atoms
INTERmolecular bonding
attractions between molecules due to dipoles on the molecules or shifting e- clouds (melting point, boiling p. state @ room temp)
bond energy
the potential energy at the most stable point (shorter bonds are stronger than longer ones, values are neg.)
bond polarity
measure of how equally or unequally the electrons in a covalent bond are shared
electron-domain
bonds around central atom
non bonding domain
lone pairs (not part of e- domains geometry)
bonding domain
bond between atoms
2 e- domains
linear e- domain gemoetry
3 e- domains
trigonal planar domain gemonetry
trigonal planar bond angle
120
4 e- domains
tetrahedral domain geom
5 e- domains
trigonal bipyramidal domain geom
6 e- domains
octahedral domain geom
formal charge
the charge an atom would have if each bonding e- pair between the atoms in a molecule were equally shared between its two atoms
best structure formal charge
when negative charge is on most electronegative strucure
molecular geometry
shape based off of e-domain gemonetry including lone pairs
e- domains gemetry
shape based of bonding domains
vesper theory
how different e- domains determine molecular geometry
lewis dot structure
the octet rule