chapter 8 + 9 vocab Flashcards

1
Q

linear bond angle

A

180

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2
Q

tetrahedral bond angle

A

109.5

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3
Q

trigonal bipyramindal angle

A

90 and 120

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4
Q

what shape do you get when removing one atom from the vertex of a tetrahedron (lone pair)

A

trigonal pyramindal

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5
Q

what shape do you get when removing two atoms from the vertex of a tetrahedron (2 lone pairs)

A

bent shape

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6
Q

bent shape bond angle

A

104.5

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7
Q

trigonal pyramidal bond angle

A

107

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8
Q

lattice energy

A

the energy required to separate 1 mole of an ionic compound into its gaseous ions. A large, positive lattice energy indicates a strong attraction

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9
Q

sp-hybrizadation

A

orbitals on the central atom mix to form hybrid orbitals
number of hybrid orbitals=number of orbitals that are mixed
hybrid number= 1 less than e- domains

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10
Q

sp- hybridization shape

A

linear (or bent)

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11
Q

sp^2-hybridization shape

A

trigonal planar

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12
Q

sp^3-hybridization shape

A

tetrahedral

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13
Q

electronegativity difference

A

shared e- shift to more electronegative element

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14
Q

electronegativity across a period

A

increases

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15
Q

electro.neg. down a group

A

decreases

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16
Q

resonance

A

all bonds are equivalent in length and energy. (double bonds can be on any side)

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17
Q

ionic bond`

A

when cation and anion bond creating a rigid well defined 3 dimensional arrangement

18
Q

cations

A

metals

19
Q

anions

A

nonmetals

20
Q

covalent bond

A

formed by 2 atoms by sharing one or more pairs of e-

21
Q

polar

A

one atom exerts a greater attraction for the bonding electrons than the other

22
Q

nonpolar

A

electrons shared eqully

23
Q

double and triple bonds

A

as # of bonds increase, bond strength increases, length decreases

24
Q

INTRAmolecular bonding

A

bonds between atoms or ions that create new compounds. e- are transfered or shared between atoms

25
Q

INTERmolecular bonding

A

attractions between molecules due to dipoles on the molecules or shifting e- clouds (melting point, boiling p. state @ room temp)

26
Q

bond energy

A

the potential energy at the most stable point (shorter bonds are stronger than longer ones, values are neg.)

27
Q

bond polarity

A

measure of how equally or unequally the electrons in a covalent bond are shared

28
Q

electron-domain

A

bonds around central atom

29
Q

non bonding domain

A

lone pairs (not part of e- domains geometry)

30
Q

bonding domain

A

bond between atoms

31
Q

2 e- domains

A

linear e- domain gemoetry

32
Q

3 e- domains

A

trigonal planar domain gemonetry

33
Q

trigonal planar bond angle

A

120

34
Q

4 e- domains

A

tetrahedral domain geom

35
Q

5 e- domains

A

trigonal bipyramidal domain geom

36
Q

6 e- domains

A

octahedral domain geom

37
Q

formal charge

A

the charge an atom would have if each bonding e- pair between the atoms in a molecule were equally shared between its two atoms

38
Q

best structure formal charge

A

when negative charge is on most electronegative strucure

39
Q

molecular geometry

A

shape based off of e-domain gemonetry including lone pairs

40
Q

e- domains gemetry

A

shape based of bonding domains

41
Q

vesper theory

A

how different e- domains determine molecular geometry

42
Q

lewis dot structure

A

the octet rule