Chapter 7: Chemical Reactions: Energy, Rates, and Equilibrium Flashcards

1
Q

potential energy

A

stored energy

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2
Q

kinetic energy

A

the energy of an object in motion

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3
Q

heat

A

a measure of the transfer of thermal energy

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4
Q

bond dissociation energy

A

the amount of energy that must be supplied to break a bond and separate the atoms in an isolated gaseous molecule; if this is greater, then it has a more stable chemical bond

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5
Q

endothermic

A

a process or reaction that absorbs heat (+H)

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6
Q

exothermic

A

a process or reaction that releases heat (-H)

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7
Q

heat of reaction/enthalpy change

A

the difference between the energy of bonds broken in reactants and the energy of bonds formed in products

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8
Q

enthalpy

A

a measure of the amount of energy associated with substances involved in a reaction

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9
Q

spontaneous process

A

a process or reaction that, once started, proceeds on its own without any external influence

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10
Q

entropy

A

a measure of the amount of molecular disorder in a system

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11
Q

entropy change (S)

A

a measure of the increase in disorder (+) or decrease in disorder (-) as a chemical reaction or physical change occurs

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12
Q

activation energy

A

the amount of energy needed for reactants to surmount the energy barrier to reaction; determines the reaction rate

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13
Q

reaction rate

A

a measure of how rapidly a reaction occurs

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14
Q

activation energy

A

the amount of energy needed for reactants to surmount the energy barrier to reaction; determines the reaction rate

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15
Q

reaction rate

A

a measure of how rapidly a reaction occurs

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16
Q

reversible reaction

A

a reaction that can go in either direction

17
Q

chemical equilibrium

A

a state in which the rates of forward and reverse reactions are the same

18
Q

Le Chatelier’s Principle

A

when a stress is applied to a system at equilibrium the equilibrium shifts to relieve the stress