Chapter 7 Flashcards
The energy content of a food can be considered as
The amount of energy that would be produced if the body converted it to CO2+H2O by aerobic metabolism
How the energy content of food is measured
The heat released is termed the heat of combustion and can be
measured in a bomb calorimeter
What is one calorie
calorie = amount of heat required to increase the temperature of 1
gram of H 2 O by 1 C
What is the conversion betwen calories and joules
1 J = 0.239 cal 1 cal = 4.184 J)
Food calories are usually measured in ___
Kilocalories
Why measuring food by burning in a bomb calorimeter is not reliable and give the example
because it does not take into
account digestibility .+ if you take apples, you will need to take seeds, because we usually do not eat them, as well as remove the peel maybe, etc.
Combustion of 1 g of cellulose produces the same amount of
heat as combustion of 1 g of starch whereas the human body
completely hydrolyzes starch to its glucose subunits but cannot digest
cellulose.
If the calorimeter is not the reliable source of info about caloric properties of food, so how it is measured
standard values for the heat of combustion of each class of macronutrients have been adopted.
Accordingly, a common method is
to use analytical chemistry to
determine the amounts of each of the macronutrients in a food
sample and then multiply each amount by the corresponding standard
value.
Carbohydrates: calories and joules
4 kcal
16.7 kj/g
Protein: calories and joules
4 kcal/g
16.7 kj/g
Fat: calories and joules
9 kcal/g
37.7 kj/g
Alcohol: calories and joules
7 kcal/g
29.3 kcal/g
Organic acids :calories and joules
3 kcal/g
12.5 kj/g
Polyols(sugar alcohols):calories and joules
2.4 kcal/g
10 kj/g
Fiber : calories and joules and why it has calories if we day that we cannot digest it
2 kcal/g
8.4 kj/g
calories due to organic acids that are going to be metabolized by bacteria
Polyols have calories, but we still them use as sucrose replacer, why?
1) The way how sugar alcohols metabolized in a different way in our body , so they wont be converted to fat
2) More sweet than sucrose
Why fat have so many calories
because it has a much higher number of carbon atoms per
gram , and accordingly combustion to CO 2 involves reaction with a
larger number of O 2 molecules
In addition to their higher energy content, fats are a compact way to
store energy because they are nonpolar and therefore not hydrated ;
The longer the fatty acid, ____ the caloric intake
higher
Calorie reduced foods are usually formulated by ___
( using alternative sweeteners to reduce calories derived from sugars
or
(ii) using carbohydrate or protein based fat replacers to mimic certain
functional properties of fat
What are nutritive sweeteners
Sugar alcohols polyols ), e.g., xylitol, sorbitol, maltitol, mannitol, etc.:
these are “ nutritive sweeteners ” because they contribute calories
(1.5 3 kcal/g).
Similar properties of sugar and sugar alcohols
- Most the functional properties with fewer calories, like sugar alcohols, they bind water by hydrogen bonding, which contributes
to the moistness of baked products.
What are non-nutritive sweeteners
are substances that do not contribute to the
calorie content of the food. These very sweet substances are used to
replace sugars as a sweetening agent but cannot provide other
functional properties of sugars.
What sweetener have bitter aftertaste and 200X more sweet than sucrose
Acesulfame-K
Structure of aspartame
is the methyl ester of a dipeptide phenylalanine +
aspartic acid
Does aspartame have caloric content
Yes, the same as proteins
How many times aspartame is more sweet than sucrose
200
A sweetener than is similar to aspartame , but cannot be hydrolyzed by enzymes
neotame
neotame sweetness
7000-13000
Structure of sucralose
is a sucrose molecule in which three of the hydroxyl groups
are replaced by chlorine atoms
Sweetness of sucralose
600
What is simplesse
is a reduced calorie fat replacer made of
microparticulated milk and/or egg white proteins
Simplesse and ___ are used in fat reduced products
Microcrystaline cellulose
Why simplesse is used as fat replace r
Microparticulation provides the mouthfeel of fat with less than half the
calories.
Where simplesse cannot be used
the thermal denaturation
What is olestra
is a sucrose molecule in which 6 8 of its hydroxyl groups are
esterified with fatty acids
Olestra properties
It provides the same properties as fats, is heat stable at frying
temperatures, and is indigestible (0
Is olestra used?
No, because of diarrhea
Carbohydrate-fat replacers: examples and digestibility
Carbohydrate based fat replacers may contribute calories (e.g.,
starch gels) but often are indigestible polysaccharides .
Roles of carbohydrates in digestion
Carbohydrates : both sugars and starch assist the body in utilizing fats
more efficiently by producing organic acids that are required to
convert fats fully to CO 2 and water ( extract maximum energy from
fat metabolism).
The roles of indigestible carbohydrates ( fiber ) in promoting health
have been increasingly recognized over the past few decades.
Fats and oils provide
: fats/oils provide the essential fatty acids ω 3 and ω 6
fatty acids) and are important carriers of fat soluble vitamins
Protein needs are the greatest at what point of time
Protein needs are greatest during pregnancy and childhood (growth).
What plant sources lack lysine
Wheat, corn and rice proteins
Legumes (soybean) lack
Methionine
How protein quality is measured
Protein digestibility and the effects of amino acid
balance/imbalance
What is protein efficiency ratio (PER)
Measure of animal’s weight gain/gram of protein consumed
What is BV
Biological value measures overall nitrogen retention
Calculated= nitrogen in protein consumed-nitrogen excreted
Net protein utilization formula
NPU=BV*digestibility factor
Net protein value (NPV) formula
NPU*%protein in food
What is PDCAAS
Protein Digestibility Corrected Amino Acid Score (PDCAAS)
The protein quality rankings are determined by comparing the amino acid
profile of the specific food protein against a standard amino acid profile
with the highest possible score being a 1.0.
1.0 score means, after digestion of the protein, it provides per unit of
protein 100% or more of the indispensable amino acids required .
What is DIAAS
Digestible Indispensable Amino Acid Score (DIAAS)
It determines amino acid digestibility, at the end of the small intestine ,
providing a more accurate measure of the amounts of amino acids
absorbed by the body and the protein’s contribution to human amino acid
and nitrogen requirements.
Is PDCAAS is accurate
PDCAAS is based on an estimate of crude protein digestibility determined
over the total digestive tract, and values stated using this method generally
overestimate the amount of amino acids absorbed
What is the vitamin
Organic compounds (other than essential amino acids and essential fatty acids) required in the food supply to maintain health and proper functioning of the body.
Food processing and vitamin content
Many food processing operations reduce the vitamin content or
availability in foods.