Chapter 6 - Thermal Physics Flashcards
How do we observe Brownian motion?
- look at smoke through a microscope, see smoke grains move jerkily and erratically.
- result of smaller O2 and N particles knocking them. Due to erratic motion of smoke, it shows that air molecules must too be MOVING and have HAPHAZARD motion.
Pressure = ?
The force exerted per unit area of the surface.
SAS of particles in a solid?
Slow, regular, close
SAS of particles in a liquid?
Medium speed, touching but irregular arrangement and close spacing
SAS of particles in a gas?
Fast, no arrangement, large spacing
Describe change of state as heat is added to a solid.
1) increase in temp of solid
2) no increase briefly due to energy being used to break solid bonds
3) increase in temp of liquid
4) no increase for longer time due to energy being used to break liquid bonds (more to break than solid to liquid so time is longer)
5) increase in temp of gas
Why is water more dense than ice?
The arrangement of water is more compacted than ice, since the regular arrangement of particles in ice creates large gaps between particles.
What energy increases when particles break free of their neighbours?
Their electrical potential energy (EPE).
Describe electrical potential energy against separation graph?
- at low separation, EPE is large negative.
- as it increases, separation does too but at EPE proportional to -1/r
- EPE reaches 0 when the particles are completely separated.
What 4 things happen when a substance (eg. Water) is melting/ boiling (flat part of graph)?
- energy is input
- temperature doesn’t change
- molecules break bonds between each other
- EPE increases
Latent heat of fusion = ?
The energy which must be supplied to cause a substance to melt at a constant temperature.
Latent heat of vaporisation = ?
The energy which must be supplied to cause a substance to boil at a constant temperature.
Evaporation = ?
The process by which a liquid becomes a gas at a temperature below its boiling point.
What is formed due to evaporation?
Vapour.
Why does evaporation happen?
- in a liquid particles move about
- some move fast enough to break away from the liquid completely
- some return by chance
- but the result is a net outflow of molecules so eventually a liquid will evaporate completely