CHAPTER 6-8 Flashcards
V-is important as physical evidence because it breaks and pieces are scattered at the crime scene and on the suspect.
GLASS
-is important as physical evidence because it breaks and pieces are scattered at the crime scene and on the suspect.
GLASS
-The evidence maybe fragments of a headlight leads found at the scene of a hit and run accident, window glass from the scene of robbery, or glass through which a bullet was fired.
GLASS
– This refers to a supercooled liquid which possesses high viscosity and rigidity.
GLASS
-It is a non – crystalline inorganic substance.
GLASS
-is usually composed of oxides like SiO (silica), B O (boric oxide), P O (phosphorous pentoxide).
GLASS
-It is made of silica sand and other metallic oxides.
GLASS
-This may contain incidental impurities and the presence of these substances is invaluable for the identification and comparison of glass by spectrographic analysis.
GLASS
______ like window and plate which are made in mass production is fairly uniform in composition.
GLASS
is the most important oxide.
SILICA
-It is the base of commercial glasses.
SILICA
is for fluxing, durability and reduction of viscosity.
Oxide
has also presence of trace elements which may be sufficient to establish or negate the fact of a common source for two samples of glass.
Gas
- base of commercial glass
SILICA
–basic foundation of glass
SILICA
SILICA chemical name
SiO2
SODA name
Na2O
-acts as flux for silica
SODA
-gives the glass chemical durability which it otherwise lack because of the water – soluble Na2O
LIME
Lime name
CaO
-present as impurity or substitute for CaO
MAGNESIS
MAGNESIS name
MgO
–substitute for lime
MAGNESIS
-gives the glass greater chemical durability lower coefficient of expansion, and greater freedom from devitrification
ALUMINA
ALUMINA name
Al2O2
-for chemical durability and resistance to devitrification
POTASH
–strong chemical
–for high rise building
POTASH
POTASH name
KO
3R RULES
- POINT OF IMPACT
- RADIAL FRACTURE
- CONCENTRIC FRACTURE
-The most important problem commonly referred to a forensic chemist is the comparison of two or more samples of glass.
ANALYSIS OF GLASS
– an instrumental method of analysis which determines the presence of trace elements.
SPECTROGRAPHIC TEST
-Shows the constituent elements of glass.
SPECTROGRAPHIC TEST
-It will not give sufficient information to establish is the origin of the samples examined.
SPECTROGRAPHIC TEST
-A rapid examination and an adequate method for glass analysis since it requires only a small amount of sample.
SPECTROGRAPHIC TEST
-In the absence of trace elements, it may be difficult to determine whether two samples of common type of glass are identical.
SPECTROGRAPHIC TEST
-If similar trace elements are found of both samples it is obvious they come from the source.
SPECTROGRAPHIC TEST
– not as effective as the spectrographic analysis.
X – RAY DIFFRACTION TEST
-It determines the type of pattern of glass.
X – RAY DIFFRACTION TEST
-The type of pattern depends upon the composition of glass.
X – RAY DIFFRACTION TEST
– the most sensitive method of determining differences of composition in glass samples and depends upon the study of the physical properties of glass.
PHYSICAL PROPERTIES EXAMINATION
-Properties like specific gravity and density, refractive index.
PHYSICAL PROPERTIES EXAMINATION
-Density and refractive index can be measured with great accuracy.
PHYSICAL PROPERTIES EXAMINATION
is an especially important physical property from the viewpoint of the forensic chemist.
Density or specific gravity
– a rapid and convenient method of determining the density of small glass fragments.
FLOTATION METHOD
-Procedure and principle are the same as in soil
FLOTATION METHOD
– method used to measure the refractive index of a glass.
IMMERSION METHOD
-It is difficult to distinguish between two samples of glass by density and refractive index.
IMMERSION METHOD
-It may be mentioned that two glass from independent sources can vary conceivably have the same index of refraction or the same density but it is quite improbable that they would have both index of refraction and density the same.
IMMERSION METHOD
– determines the differences in the appearance of the fluorescent thus indication of physical and chemical differences.
ULTRAVIOLET LIGHT EXAMINATION
– optical glass and other fine glasswares are usually _____
POLISH MARKS
-In the _____ of glass fine marks are often left on the surface which can sometimes serve as a basis of comparison.
POLISH MARKS
The surface is cleaned with alcohol and then etched by spraying with ________. The act is permitted to remain on the surface for several minutes. The glass is again washed with alcohol and dried. If the surface is illuminated by oblique tight, a photograph can be made to show the polish marks.
The surface is cleaned with alcohol and then etched by spraying with 20 to 25% hydrofluoric acid. The act is permitted to remain on the surface for several minutes. The glass is again washed with ______ and dried. If the surface is illuminated by oblique tight, a photograph can be made to show the polish marks.
alcohol
____ first bends a little owing to its elasticity
glass