Chapter 5 Flashcards
Firefighting personnel should have an understanding of combustion and fire dynamic principles and be able to use them for fire scene size up and assessment of fire conditions both upon initial arrival and continuously over the course of the incident.
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The combustion reaction can be characterized by four components: the fuel, the oxidizing agent, the heat, and the uninhibited chemical chain reaction.
The difference between the fire tetrahedron model and the fire triangle model of combustion is the inclusion of the chemical chain reaction.
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The chemical chain reaction provides the ability to sustain flames.
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The fire triangle will only support a flash or flame or combustion in the condensed phase, such as glowing embers or hot charcoal.
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A fuel is any substance that sustains combustion under specified environmental conditions.
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The majority of fuels encountered are organic, which means that they are carbon-based and may contain other elements such as hydrogen, oxygen, and nitrogen in varying ratios.
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The term fuel load is used to describe the amount of fuel present within a defined space, usually within a compartment.
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Increased synthetic fuel loads and new construction materials with higher heat of combustion lead to higher heat release rate.
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Pyrolysis is a process in which the solid fuel is decomposed, or broken down, into simpler molecular compounds by the effects of heat alone.
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Pyrolysis precedes combustion and continues to support the combustion after ignition occurs.
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the application of heat causes vapors or pyrolysis products to be released where they can burn when in proper mixture with air and a sufficient ignition source is present, or if the fuel’s autoignition temperature is reached.
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If the thermal exposure to the fuel is increased, the rate of pyrolysis may increase.
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Heats of combustion typically range from 10 Mj/kg to 4Mj/kg with hydrocarbon-based products having two to three times higher values than natural products.
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Air in the earth’s atmosphere is made up of approximately 21 percent oxygen and 78 percent nitrogen.
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Every fuel air mixture has an optimum ratio at which point the combustion will be most efficient. This ratio occurs at or near the mixture known by chemists as the stoichiometric ratio.
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When the amount of air is in balance with the amount of fuel, the burning is referred to as stoichiometric.
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The heat release rate of a fire is variable over time and is dependent on the fuel load characteristics, oxygen available, and enclosure characteristics.
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Heat flux is the measure of the rate of heat transfer to a surface, expressed in kilowatts per meter squared.
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The higher the heat flux from a fire to surface, the faster the temperature of the surface will increase.
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