Chapter 5 Flashcards

1
Q

In 1860 who presented a method for accurately measuring the relative atomic masses of the elements?

A

Stanislao Cannizzaro

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2
Q

Who published their first period table in 1869? How did they organize it?

A

Dimitri Mendeleev
- placed known elements in order using their atomic masses
- recognized that certain properties repeated themselves “peridoically”
- rearranged the elements so that elements with similar properties appeared together in his table
- his procedure left empty spaces from elements that had not been discovered

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3
Q

In 1911 Henry Mosley discovered what?

A

That the periodic table fit better when the elements were placed in order according to their increasing positive charge

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4
Q

What did Moseley’s work lead to?

A

The modern definition of atomic number and that atomic number is the basis for organization of the periodic table not atomic mass

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5
Q

What is the periodic law?

A

The physical and chemical properties of the elements are periodic functions of their atomic numbers

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6
Q

How is the periodic table arranged?

A

Arranged in order of their atomic numbers so that elements with similar properties fall in the same column or group

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7
Q

A group/family

A

The vertical columns of the periodic table

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8
Q

Period

A

The horizontal rows of the periodic table

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9
Q

What are the noble gases?

A

The group 18 elements which are not reactive (inert)

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10
Q

What are lanthanides

A

Elements 58-71 at the bottom of the periodic table that are very similar in properties; represent the 4th energy level “f” orbital block elements from period 6

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11
Q

What are actinides?

A

Elements 90-103 are all radioactive and represent the 5th energy level “f’” orbital block elements from period 7

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12
Q

In each of groups 1-18, the differences between the atomic numbers of successive elements are 8.8.18.18.32

A
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13
Q

The electron configuration of an atom’s highest occupied energy level governs…

A

the atom’s atomic properties

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14
Q

How is the length of each period determined?

A

By the number of electrons that can occupy the sublevels being filled in that period

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15
Q

S-Block Elements

A

Groups 1 and 2; the s orbital is being filled in the energy level equal to the period number

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16
Q

Alkali metals

A

Group 1 metals; so reactive that do not exist as pure elements in nature

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17
Q

Alkaline-earth metals

A

Group 2 metals that also are very reactive and do not exist alone in nature

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18
Q

P-block elements

A

13-18; the 3 “p” orbitals are being filled in the energy level equal to the period number

19
Q

Halogens

A

Group 17 elements

20
Q

D-Block elements (transition metals)

A

3-12, in which 5 “d” orbitals are being filled in the energy level equal to the period # minus 1

21
Q

F block elements

A

two rows at the bottom of the periodic table that represent 7b “f” orbitals being filled in the energy level that is equal to the period number minus 2

22
Q

What is atomic radius

A

One-half the distance between the nuclei of identical atoms that are bonded together

23
Q

As you go across a period the positive charge of the nucleus _______, the pull exerted on the electron cloud _______ and the atomic radius of the elements decreases across the period.

A

increases; increases

24
Q

As you move down a group, each successive element adds an energy level so the atomic radii _________ down a group

A

increase

25
Q

What is an ion?

A

An atoms or group of atoms that has a positive or negative charge

26
Q

What is ionization?

A

Any process that results in the formation of an ion

27
Q

What is ionization energy?

A

The amount of energy required to remove one electron from a neutral atom of an elements

28
Q

Ionization energies of the main group elements ________ across a period

A

increase

29
Q

Ionization energies of the main group elements usually _________ down a group

A

decrease

30
Q

Group 1 metals have the __________ ionization energies. Why?

A

lowest; they love electrons easily

31
Q

Group 18 have ___________ ionization energies. Why?

A

high; don’t lose electrons easily

32
Q

What is electron affinity?

A

the energy change that occurs when an electron is acquired by a neutral atom

33
Q

What is a cation?

A

An ion with a positive charge due to the loss of electrons

34
Q

Anion

A

An ion with negative charge due to the gain of electrons

35
Q

Halogens ______electrons most readily. What dies this cause?

A

gain; high reactivity

36
Q

When atoms become ions their radius…

A

changes

37
Q

Formation of a cation leads to a ______ in atomic radius

A

decrease

38
Q

Formation of an anion leads to a ________ in atomic radius.

A

increase

39
Q

What are valence electrons?

A

Electrons available to be gained, lost, or shared by atoms in the formation of chemical bonds to make compounds

40
Q

Where are valence electrons?

A

In the highest energy levels and often located in incompletely filled orbitals

41
Q

What is electronegativity

A

A measure of the ability of an atom in a chemical compound to attract electrons from another atom in the compound

42
Q

Electronegativity tends to ________ across a period and either _________ or remain ________ down a group.

A

increase; decrease; the same

43
Q

What is the most electronegative of the elements?

A

Fluorine (F)