Chapter 4 Quiz Flashcards

1
Q

How is light as a wave?

A

A type of electromagnetic radiation, along with X-rays, ultraviolet and infrared light, microwaves, and radio waves.

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2
Q

Waves have a _______ ______ and can be measured by ________ & _________.

A

repetitive nature; wavelength; frequency

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3
Q

What are the units of wavelength?

A

cm or nm

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4
Q

What are the units for frequency?

A

Waves/sec or hertz (Hz)

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5
Q

How are frequency and wavelength related to each other?

A

c=wavelength x frequency

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6
Q

What is c

A

c=speed of light or 3.00 x 10^8 m/s

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7
Q

How is light as a particle?

A

By the photoelectric effect, when the emissions of electrons from metal when light shines on it
Light has to have a minimum frequency for this to occur

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8
Q

What is Planck’s theory and constant?

A
  • Objects do not emit electromagnetic energy constantly
  • Instead energy is emitted in small specific packets called quanta
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9
Q

What is a quantum of energy?

A

The minimum amount of energy that can be lost or gained by an atom

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10
Q

E=hv

A

Equation showing relationship between quantum of energy and frequency

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11
Q

Who expanded on Planck’s theory and how?

A

Einstein expanded on Planck’s theory by introducing that light has a dual wave-particle nature.

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12
Q

Light can be thought of as …

A

a stream of particles

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13
Q

What is a photon?

A

A particle of electromagnetic radiation w/no mass and carrying a quantum of energy

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14
Q

What is ground state?

A

Lowest energy state of an atom

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15
Q

What is excited state

A

An atom has a higher potential energy than in its ground state

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16
Q

What happens when an electron returns to ground state?

A

It gives off energy in form of electromagnetic radiation

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17
Q

What did specific frequencies of light and not a continuous spectrum show scientists?

A

Electrons exist in specific energy states

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18
Q

What did the Bohr Model propose?

A

A hydrogen-atom model that linked the atom’s electron to photon emission

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19
Q

According to the Bohr model…

A

the electron can circle the nucleus only in allowed paths or orbits​

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20
Q

Electron and atoms are in the lowest energy state when the electron is…

A

in the orbit closest to the nucleus​

21
Q

Energy of the electron is higher when the electron is in orbit…

A

successively farther from the nucleus

22
Q

What were the issues with Bohr’s Model?

A
  • The model does not explain atoms with more than one electron
  • Does not explain the chemical behavior of atoms
23
Q

Behavior of electrons is similar to…

A

the behavior of waves

24
Q

When can electron waves exist?

A

Only at certain frequencies, which correspond to specific energies

25
Q

How are electrons detected?

A

By their interaction with photons, but the photons knock the electron off its course

26
Q

What is the Heisenberg Principle?

A

It is impossible to determine simultaneously both the position and velocity (speed) of an electron

27
Q

What did the Schrodinger Wave Equation develop?

A

an equation that treated electrons in atoms as waves and quantization of electron energies was an outcome of the equation.

28
Q

What is the quantum theory?

A

mathematically describes the wave properties of electrons and other very small particles. ​

29
Q

What are orbitals?

A

3D region around the nucleus that indicates the probable location of an electron.​

30
Q

What are the conclusions and beginnings of the Quantum Atomic Theory?

A
  • Wave functions allow us to determine the probability of finding an electron at a given place around the nucleus
  • Electrons don’t travel in neat orbits like Bohr proposed. They exist in certain regions called orbitals
31
Q

What are quantum numbers?

A

The properties of atomic orbitals and the properties of electrons in orbitals?

32
Q

What are the principals of Quantum Number?

A
  • Symbolized by n
  • Indicates the main energy level occupied by the electron
  • As n increases the electron’s energy and its distance from the nucleus increases
33
Q

Can more than one electron have the same n value? Are they in the same shell?

A

Yes; yes

34
Q

The total number of orbitals in each shell or energy level is…

A

n^2

35
Q

What are electron configurations?

A

The arrangement of electrons in an atom

36
Q

Does each element have a unique electron configuration?

A

Yes

37
Q

What is ground -state electron configuration?

A

The lowest energy arrangement of the electrons for an element

38
Q

What is Aufbau Principle?

A

Electrons fill the lowest energy orbitals first

39
Q

What is Orbital Order?

A

1s,2s,2p,3s,3p,4s,3d,,4p,5s,4d,5p,6s,4f,5d,6p,7s,7p

40
Q

S orbital has a max subscript of…

A

2

41
Q

P orbital has a max subscript of…

A

6

42
Q

D orbital has a max subscript of…

A

10

43
Q

F orbital has a max subscript of…

A

14

44
Q

What is the Pauli Exclusion Principle?

A

Each orbital can hold TWO electrons with opposite spins.

45
Q

What is Hund’s Rule?

A

Within a sublevel, place one electron per orbital before pairing them.

46
Q

What is Noble Gas Configuration?

A

A shorthand method of writing the electron configuration?

47
Q

What is Planck’s constant?

A

6.626 x 10^-31

48
Q
A