Chapter 5 Flashcards

1
Q

why do chemical bonds form

A

to lower potential energy between charged particles

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2
Q

Exceptions to Octet Rule

A

Boron wants 6
Aluminum wants 6
Be wants 4

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3
Q

Who does the octet rule apply to

A

main group elements

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4
Q

single non-bonding electron

A

radical

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5
Q

non-bonding pair of electrons

A

localized on the atom (belong to only one atom), in atomic orbitals

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6
Q

coordinate covalent bond

A

electrons that form the bond both came from the same atom

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7
Q

Electronegativity

A

ability of an atom to attract electrons to itself in a covalent bond

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8
Q

EN trend

A

increases across a period, decreases down a group

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9
Q

EN of F

A

4.0

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10
Q

EN of C

A

2.5

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11
Q

Difference in EN of nonpolar covalent

A

0-0.4

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12
Q

Difference in EN of polar covalent

A

0.4-2.0

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13
Q

Difference in EN of ionic

A

2.0+

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14
Q

Dipole moment

A

shift in electron density, uneven distribution

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15
Q

Magnitude of dipole moment

A

µ=qr
q=charge of electron in Coulumbs
r is in meters
theoretical value, if electron were fully transferred

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16
Q

Larger magnitude of dipole moment

A

more polar the bond

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17
Q

Percent Ionic Character

A

actual dipole moment/theoretical dipole moment

18
Q

elements that can have expanded octet

A

n=3 and higher (d orbitals)

19
Q

Best Lewis structure

A

greatest resonance contributor

20
Q

negative formal charge

A

most EN atom, exceptions if needed to complete octet

21
Q

Bond energy

A

amount of energy needed to break 1 mole of that bond in the gas phase, also called bond enthalpy, delta H, positive, endothermic, absorbs energy

22
Q

greater bond energy

A

stronger bond

23
Q

1 Angstrom

A

10^-10 meters

24
Q

straight line bond

A

bond is in plane of paper

25
Q

dashed wedge bond

A

bond is behind the paper

26
Q

solid wedge bond

A

bond is coming out of the paper

27
Q

bond angles

A

ideal, not always exact

28
Q

2 bonds, 0 lone pairs

A

Electronic Geometry: linear
Molecular Geometry: linear
180 degrees
sp

29
Q

3 bonds, 0 lone pairs

A

EG: trigonal planar
MG: trigonal planar
120 degrees
sp2

30
Q

2 bonds, 1 lone pair

A

EG: trigonal planar
MG: bent
120 degrees
sp2

31
Q

4 bonds, 0 lone pairs

A

EG: tetrahedral
MG: tetrahedral
109.5 degrees
sp3

32
Q

3 bonds, 1 lone pair

A

EG: tetrahedral
MG: trigonal pyramidal
109.5 degrees
sp3

33
Q

2 bonds, 2 lone pairs

A

EG: tetrahedral
MG: bent
109.5 degrees
sp3

34
Q

5 bonds, 0 lone pairs

A

EG: trigonal bipyramidal
MG: trigonal bipyramidal
120, 90, 180
sp3d

35
Q

4 bonds, 1 lone pair

A

EG: trigonal bipyramidal
MG: seesaw
120, 90, 180
sp3d

36
Q

3 bonds, 2 lone pairs

A

EG: trigonal bipyramidal
MG: T-shaped
120, 90, 180
sp3d

37
Q

2 bonds, 3 lone pairs

A

EG: trigonal bipyramidal
MG: linear
120, 90, 180
sp3d

38
Q

6 bonds, 0 lone pairs

A

EG: octahedral
MG: octahedral
180, 90
sp3d2

39
Q

5 bonds, 1 lone pair

A

EG: octahedral
MG: square pyramidal
180, <90
sp3d2

40
Q

4 bonds, 2 lone pairs

A

EG: octahedral
MG: square planar
180, 90