Chapter 2 Flashcards

1
Q

Amplitude

A

The height of the wave, determines intensity and brightness, amount of photons

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2
Q

Wavelength

A

distance between crests, determines the color, longer wavelength equals less energy

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3
Q

frequency

A

number of cycles that pass through a stationary point in a given period of time, Hz, 1 cycle per second, 1/s, directly proportional to the speed at which the wave is traveling, inversely proportional to wavelength

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4
Q

Electromagnetic Spectrum from Lowest Energy to Highest Energy

A

Low Frequency/Long Wavelength
1. Radio
2. Microwave
3. Infrared
4. Visible Light
5. Ultraviolet
6. X-Ray
7. Gamma Ray
High Frequency/Short Wavelength

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5
Q

Quantized

A

contained in energetic specific amounts, not continuum

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6
Q

Photoelectric Effect

A

When light was shone on a metal surface, electrons are ejected from the surface of the metal which completed an electric circuit

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7
Q

ROYGBIV

A

BIV has shorter wavelength and more energy

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8
Q

Planck

A

He believed there were discrete and specific energy levels. He hypothesized that an oscillator must gain/lose energy in whole numbers, correspond to the difference between 2 levels

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9
Q

Quanta or Photons

A

light energy delivered to the atoms in packets, proposed by Einstein

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10
Q

Einstein’s second proposal

A

when an electron in the metal absorbs a photon of light, it gains the energy required to escape from the metal

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11
Q

Threshold Frequency

A

minimum frequency

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12
Q

Constructive Interference

A

same wavelength that lines up doubles amplitude

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13
Q

Destructive Interference

A

same wavelength that lines up opposite cancels out amplitude

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14
Q

White light

A

totality of wavelengths/frequencies in the visible portion of the EM spectrum

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15
Q

Emission Spectrum

A

black background with colored lines, shows which colors are emitted when the electron jumps down in energy, lines indicate that only certain energies are allowed for the electron in that atom

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16
Q

Absorption Spectrum

A

color background with black lines, colors blacked out are the colors that are absorbed when the electron jumps up in energy

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17
Q

Neils Bohr Model

A

energy in the atom is quantized, orbits are in stationary states, electrons emit radiation when the jump from an orbit of higher energy to an orbit of lower energy, distance between orbits are determined by energy of the photon of light produced

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18
Q

Wavelength v Atomic/Nuclear Dimensions

A

When the wavelengths are comparable to atomic or
nuclear dimensions, it is then that the wave-particle
duality is important

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19
Q

Heisenberg’s Uncertainty Principle

A

the more one knows about the location/position of the electron, the less one knows about the momentum/velocity of the electron, can be observed as either a wave or a particle, never both at the same time, limited by the choice in observation

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20
Q

Determinacy

A

definite, predictable future

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21
Q

Indeterminacy

A

indefinite future, can only predict probability that an electron will be found in a particular region (at an E, at a radius) using statistical functions

22
Q

Node

A

region with no electron density, zero point energetically

23
Q

Total number of nodes

A

n-1

24
Q

Allowed values of n

A

n=1, 2, 3, 4, …

25
Q

n=1

A

ground state, zero-point energy

26
Q

Schodinger’s Equation

A

allows us to calculate probability of finding an electron, a plot of distance versus (wave function) squared represents an orbital, technically a sublevel

27
Q

(wave function) squared

A

electron probability density, moves up and down like sin and cos

28
Q

Principal Quantum Number

A

n

29
Q

Angular Quantum Number, Bohr’s energy level

A

l

30
Q

Magnetic Quantum Number

A

m sub l

31
Q

l

A

shape, designates sub shell of the orbital

32
Q

m sub l

A

orientation of the orbital, the direction in space the orbital is aligned relative to other orbitals

33
Q

Magnetic Spin Quantum Number

A

m sub s

34
Q

m sub s

A

direction spinning in space, -1/2 or 1/2

35
Q

Z

A

atomic number

36
Q

Larger value of n

A

More energy the orbital has

37
Q

l=0

A

s

38
Q

l=1

A

p

39
Q

l=2

A

d

40
Q

l=3

A

f

41
Q

Value of l

A

0, 1, 2, …, n-1

42
Q

Allowed values of m sub l

A

-l, +1, +1, …, 0, …, l

43
Q

Degenerate

A

sub levels of the same energy

44
Q

Multi-Election atoms sublevels

A

not degenerate, ns

45
Q

How bonds are formed

A

orbitals overlap (why it’s important to understand atomic orbital shape)

46
Q

Probability Density

A

says electron is most likely to be found at nucleus, not really true

47
Q

Radial Distribution Function

A

at nucleus is zero, increases to its maximum value of 52.9 pm (for 1s), then it decreases again as r increases

48
Q

how many angular nodes in an s orbital

A

none

49
Q

number of angular nodes

A

l

50
Q

number of radial nodes

A

n-l-1

51
Q

number of degenerate orbitals

A

2l+1

52
Q

degenerate orbitals in p

A

px, py, pz