Chapter 3: Notes Flashcards

1
Q

What do structural formulas show?

A

The way in which atoms are bonded together

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2
Q

What causes a chemical bond?

A

The attraction of electrons by two atomic nuclei. the nucleus of its own atom and another atom

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3
Q

What are valence electrons?

A

The electrons that occupy the outermost energy level

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4
Q

What are the places that electrons exist in called?

A

Orbitals

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5
Q

What is an orbital?

A

A region of space where there is a high probability of finding electrons of a particular energy

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6
Q

How many electrons can an orbital be occupied by?

A

one or two electrons

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7
Q

What is a bonding electron?

A

A single electron occupying an orbital

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8
Q

What is a lone pair?

A

Two electrons occupying a filled orbital (non-bonding)

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9
Q

what determines an atoms bonding capacity?

A

The maximum number of bonding electrons

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10
Q

What is bonding capacity?

A

The number of covalent bonds formed by an atom

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11
Q

What is electronagativity?

A

The tendancy for an atom to attract electrons to itself (from other atoms) when is is chemically combined with another element

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12
Q

How is electronegativity organized in the periodic table?

A

It increases from left to right

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13
Q

What are covalent bonds?

A

They involve atoms sharing of a pair of electrons to get a full (8 electron) outer shell

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14
Q

What is ionic bonding?

A

When electrons are transferred from metals (low electronegativity) to non-metals (high electronegativity)

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15
Q

What is the result of ionic bonding?

A

The formation of positive cations and negative anions

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16
Q

What is an example of an empirical chemical formula?

A

A regular formula CH(sub)2O

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17
Q

What is an example of a molecular formula?

A

CH3OOH The h’s are separated

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18
Q

What is an example of a Lewis formula?

A

A dot diagram

19
Q

What is an example of a structural formula?

A

the line diagrams

20
Q

What is an example of the stereochemical formulas?

A

The ones that show the depth

21
Q

How do you draw the Lewis formula for polyatomic ions?

A

You add 1 extra electron for every negative charge

22
Q

What does VSEPR stand for?

A
Valence
Shell
Electron
Pair
Repulsion
23
Q

What is important for molecular shape?

A

The valence electrons of the central atoms

24
Q

What is the molecular shape determined by?

A

The positions of the electron pairs when they are the maximum distance apart

25
How do valence electrons repel each other?
Electrostatically
26
What repels more strongly: Lone pairs or bond pairs?
Lone pairs!
27
What does 2 bond pairs and 0 lone pairs form?
Linear H - Be - H
28
What does 3 bond pairs and 0 lone pairs form?
``` AX3 Triagonal planar H l B / \ H H ```
29
What do 4 bond pairs and 0 lone pairs form?
AX4 Tetrahedral. 2 at level one below one on top
30
What do 3 bond pairs and 1 lone pair form?
AX3E tetrahedral. 1 below one above and one at level
31
What do 2 bond pairs and 2 lone pairs?
AX2E2 tetrahedral V shaped
32
What does 1 bond pair and 2 lone pairs create?
AXE3. Linear
33
What are polar molecules?
Molecules that have one end that is slightly negative and one end that is slightly positive
34
what does bond polarity depend on?
The elctronegativities of the bonded atoms
35
When are covalent bonds polar?
when the atoms have dfferent negativities
36
Which side of an atom is labelled as partially negative?
The side of the atom where the electron spends more time which is around the nucleus with higher electronegativity
37
When is a covalent bond non-polar?
When there is no difference in electronegativity ex H-H
38
When is a covalent bond slightly polar?
When the difference of electronegativity is between 0.1 - 1.0 ex H -Cl
39
When is a covalent bond very polar?
When the difference of electronegativity is between 1.1 - 2.0 H - F
40
When is a bond ionic?
When the difference in electronegativity is greater than 2.1
41
What is the bond dipole?
The charge separation that occurs as a result of the different electronegativities of bonded atoms
42
What is the bond dipole represented by?
An arrow that points from lower to higher electronegativity
43
What happens in non polar molecules with a bond dipole?
the bond dipoles cancel out, leaving a molecular dipole of 0 ex. CO2
44
Why are molecules that are symetrical non-polar?
Becuase the dipole moments balance