Chapter 20 Electrochemistry Flashcards
Redox Reactions
Chemical reactions where electrons are transferred from one substance to another
Every half reaction has
Potential, or voltage
Cell potential (emf, electromotive force) can be calculated for redox reaction by
Adding the potentials for the half reactions
Ecell =
Eoxidation + Ereduction
Voltage and spontaneity are related by the equation
Delta g = -nFE^o
Delta g
Standard Gibbs free energy
n
Number of moles of electrons exchanged in the reaction
If the standard reaction potential is positive, the reaction is
Spontaneous
If the standard reaction potential is negative, the reaction is
Nonspontaneous
Voltaic or galvanic cell uses
Spontaneous redox reaction to generate electricity
Oxidation occurs at the
Anode
Reduction occurs at the
Cathode
Anode is generally viewed as
The source of electrons and given the negative designation
In oxidation, electrons are on the ___________ side
Product
Electrolysis reactions are
Nonspontaneous redox reactions driven by electrical energy
Electrolysis reactions take place in an
Electrolytic cell
Coulombs =
Amps * seconds
Electrolytic cell
Uses an outside power source to force a nonspontaneous reaction to take place
If concentrations of products are decreased, the ecell will increase
Tru
Electrochemistry
Study of electricity and chemical reactions