Chapter 20 Flashcards

1
Q

Charge (Q) is measured in

A

Coulombs

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2
Q

Faradays constant=

A

Avogadros times electron charge

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3
Q

Amperes is equal to

A

1 C/s

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4
Q

Potential

A

the potential energy of a unit charge at a particular point in a circuit
defined as the potential energy involved in moving a charge of 1 C to that point from
infinity (difficult to measure

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5
Q

Potential difference is the same as :

A

Voltage

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6
Q

Voltage is defined as :

A

1J of work required to move 1 C

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7
Q

R(Resistence)

A

obstruction of current flow

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8
Q

Ohm’s law

A

V=I

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9
Q

Ohm’s law is an approximation/always accurate

A

an approximation

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10
Q

C Capacitance

A

tendency of a device with two conductors separated by an insulator to absorb
charge when the voltage between the conductors is changed.units of FArads

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11
Q

system that incorporates
a redox reaction to produce or utilize electrical
energy.

A

Electrochemical cell

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12
Q

does work by releasing energy from a spontaneous

reaction to produce electricity : ____

A

voltaic cell

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13
Q

does work by absorbing energy from a source of electricity

to drive a nonspontaneous reaction: _____

A

electrolytic cell

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14
Q

Sum of ox states for all atoms in a neutral formula is zero

A

absorb

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15
Q

Sum of ox states of all atoms in polyatomic ion = ion charge.

A

absorb

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16
Q

Oxidation priority trends with ______

A

electronegativity

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17
Q

The oxidizing agent is the species that gets ______

A

reduced

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18
Q

The reducing agent is the species that gets _________

A

oxidized

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19
Q

The total number of electrons gained by atoms/ions of
the oxidizing agent always equals the total number of
electrons lost by the atoms/ions of the reducing agent.

A

absorb

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20
Q

Cr2O72−(aq) + Zn(s) -> Cr3+(aq) + Zn2+(aq) (acidic) balance bitch!

A

14H+ +Cr2O7 2- +3Zn -> 3Zn 2+ +7 H2O

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21
Q

MnO4−(aq) + Br−(aq)-> MnO2(s) + BrO3−(aq) (basic)

A

H2O + 2 MnO4− + Br−-> 2MnO2 + BrO3− + 2OH−

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22
Q

In these cells its necessary to Physically separate the reduction
from the oxidation

23
Q

In the cell, electrons
leave the anode and
flow through the wire to
the cathode.Which cell?

A

Voltaic cell

24
Q
As the electrons leave
the anode, the cations
formed dissolve into the
solution in the anode
compartment.
A

Voltaic cell

25
``` As the electrons reach the cathode, cations in the cathode are attracted to the now negative cathode. ```
voltaic cell
26
``` The electrons are taken by the cation, and the neutral metal is deposited on the cathode. ```
Voltaic cell
27
a | represents a ___ ____
phase boundry
28
a || represents a ____ ____
salt bridge
29
Do all voltaic cells have salt bridges?
no, they can have a porous barrier
30
Some cell reactions require an inert electrode such as platinum
absorb
31
Ecell is exactly the same as emf?
yes | Hi future me
32
For a spontaneous cell reaction Ecell>/
>
33
1 Volt =
1 joule/ coulomb
34
A cell potential is the potential ______ between two electrodes (half-cells).
difference
35
SHE is the
standard hydrogen electrode which =0
36
Increasing electronegativity increases oxidizing agent strength (how readily reduced) so the highest would be __
Fluorine
37
Li is a strong reducing agent (easily oxidized) due to it's low ______
electronegativity
38
H is 0 E because its the standard
absorb
39
The lower E value = the anode value
true
40
E is an _____ property (like density) | this means that coefficients don't change the value.
intensive
41
Negative wmax means
that work can be done by the system
42
Wmax is theoretical and cant be obtained without the lack of a current flow
true
43
For any operating cell, current ___ flow and hence w
will
44
In a concentration cell the elements are the same but the ____ is different
Molarity
45
A primary battery is:
self contained and non rechargable
46
A secondary battery is self contained and
rechargeable
47
A battery that uses a liquid electrolyte in solution
wet cell battery
48
A battery that uses a paste electrolyte
dry cell
49
Fuel cells
a voltaic cell that uses fuels (O2 and conventional fuels) to convert chemical energy into electrical energy.
50
``` Alkaline Manganese Dioxide (alkaline battery) • Lithium Manganese Dioxide • Zinc Air • Silver Oxide (button) ```
are all primary batteries
51
``` Lead-Acid (car battery) • Nickel-Metal Hydride (Ni-MH) • Nickel-Cadmium (NiCd) • Lithium Ion ```
are all secondary batteries
52
Cathodic protection, making iron behave more like a cathode prevents corrosion
Galvanized steel is coated with a sacrificial layer of | zinc so the zinc is oxidized instead of the iron.
53
In an ________ cell, electrical energy from an external source drives a nonspontaneous reaction.
electrolytic
54
a cell that uses electrical energy to drive a | nonspontaneous reaction
Electrolytic cell