Chapter 2 Flashcards
Isotopes
Different versions of the same element
same number of protons and electrons but different neutrons
Proton + Electron
Attract each other because of the electric charges
Causes the chemical behaviour
Extra neutrons in the atom (chemical behaviour)
Doesn’t change chemical
Changes physical behaviour (more or less stable)
Ions
charges
Mass number
Counts particles that have a significant mass (protons and neutrons = nucleus)
Why does the protons and electrons have to have the same number
Or they would be different elements
Atomic number
Proton number
What weighs more
Neutrons/Protons
Neutrons
What makes an ideal standard atom
Abundant and equal number of protons and neutrons
carbon
RIM
Mass of an atom of an isotope compared to 1/12 of Carbon-12
RAM
The mean mass of 1 mole of an element compared to 1/12 of Carbon-12
Mass spectrometry
Determines the RAM
Ionisation in mass spectrometry
creates positive ions
M/Z Ratio
From the acceleration and deflection of the cations
The bigger the mass, more momentum and the harder it deflects
Relative abundance
Mass spectrometry sorts ions by mass
Formula of RAM
(Mass 1 * %1) +
(Mass 2 * %2)
————————————-
100
Neon has a relative atomic mass of 20.18
The relative abundance of 20Ne is 90.92%
The relative abundance of 21Ne is 0.26%
Calculate the mass of the only other isotope?
The abundance of the remaining isotope is 100 - 90.92 - 0.26 = 8.82%
If the mass of the remaining isotope is X then:
(90.92 x 20) + (0.26 x 21) + (8.82 x X) ------------------------------------- 100 = 20.18
100 = 20.18
1823.86 + (8.82X) = 20.18 x 100
8.82X = 2018 - 1823.86
8.82X = 194.14
X = 194.14 = 22.01
So the other isotope is 22Ne = 8.82
RMM
Mass of one molecule
Transition metals for more than one ion
Oxidation numbers
tells you the amount of ions in the element
Binary compounds
Only contains two elements
= ends in -ide
Polyatomic ions
Ammonium (NH4+) Hydroxide (OH-) Nitrate (NO3-) Carbonate (CO32-) Phosphate (PO43-) Dichromate VI (CR2O72-)
How to write a formulae from ions
overall charge has to be 0 so ionic charges are balanced
Diatomic molecules
H2, N2, O2, F2, Cl2, Br2, I2
Formula unit
works out from the ionic charges is used in equation