3.2 - Determination of formulae Flashcards
Molecular formula
Number of atoms of each element in a molecule
Empirical formulae
Simplest whole number ratio of atoms of each element in a compound
RMM
compares the mass of a molecule with the mass of an atom of carbon-12
(adding the RAM of elements thats make up the molecule)
RFM
Compares the mass of a formula unit with the mass of an atom of carbon-12
(adding the RAM of elements in the empirical formula)
Hydrated
When water is part of the crystalline structure
Water of crystallisation
Blue crystals and White substance
Hydrated copper (II) Sulfate is heated and the bonds in the water are broken, leaving white anhydrous copper (II) sulfate
The 2 assumptions of experimental formula
1) hydrous and anhydrous have different colors, you know the water is removed however if the colors are similar is more difficult because you can only see the surface of the crystal
= Heat the crystal repeatedly until the mass of the residues doesn’t change (all the water is removed)
2) Salts can decompose further when heated so it becomes more difficult to see the color change