chapter 19 Flashcards

1
Q

homogeneous equilibrium

A

contains equilibrium species that all have the same state or phase

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2
Q

heterogeneous equilibrium

A

contains species that have different states or phases

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3
Q

mole fraction

A

the mole fraction of a gas is the same as its proportion by volume to the total volume of gases in the gas mixture

x(A)= number of moles of A/ total number of moles in gas mixture

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4
Q

partial pressure

A

the partial pressure p of a gas is the contribution a gas makes towards the total pressure

p(A)= x(A) x P

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5
Q

Kp

A

H2 + I2 –> 2HI

kp= p(HI)2/p(H2)xp(I2)

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6
Q

do equilibrium constants change?

A

at a set temp, K is constant and does not change despite any modifications to conc, pressure or presence of a catalyst
- k does change if the temp is changed

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7
Q

effect of temp on K- exothermic reactions

A
  • eq constant decreases w/ increasing temp

- raising temp decreases eq yield of the products

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8
Q

effect of temp on k- endothermic reactions

A
  • eq constant increases w/ increasing temp

- raising the temp increases eq yield of products

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