Chapter 19 Flashcards
- often called “redox” reactions
- involves transfer of e- between reactants (oxidation numbers change)
Oxidation-Reduction Reactions
loss of e-
oxidation
gain of e-
reduction
species that accepts e-
oxidizing agent (gets reduced)
species that donates e-
reducing agent (gets oxidized)
occurs because different elements gave different tendencies to gain or lose e-
redox reactions
charge on an atom if e- were transferred completely
- another way that allows us to keep track of electrons
Oxidation numbers (oxidation state)
- early work by Micheal Faraday (1830’s)
- amount of chemical change during electrolysis is directly proportional to amount of electrical charge that is passed thru wire
Stoichiometric Relationships in Electrolysis
the use of electrical energy to drive non spontaneous chemical reaction is called
electrolysis
the cell used to carry out electrolysis
electrolytic cell
- have a reduction potential associated with it
- natural tendency to proceed as reduction
Each half reaction in a redox reaction can be considered to
reduction potential for half reaction under standard conditions
standard reduction potential
difference in electrical potential between anode and cathode
cell potential
- electrical current flows from anode to cathode
- an electrical potential anergy difference between two electrodes
- analogous to flow of water down hill due to difference in gradational potential energy
standard reduction potentials
device that use a chemical reaction to generate electricity and is a spontaneous reaction
Galvanic Cells (Voltaic Cells)