Chapter 17.2 Flashcards
Entropy and rxn tendency
Symbol and unit
Measure of disorder or randomness of particles In a system
Symbol is change S
S=Sp-Sr
Units are KJ/mol K
Enthalpy and Rxn tendency
Most rxns in nature are Exothermic
Produce low NRG, stable products
Rxn proceed spontaneously
Who has the greatest entropy btw solids liquids and gases
S Solid<S gas
When are rxns favored to occur and where does nature go towards
When S increases
High disorder: results in low enthalpy and high entropy
Why do reactions happen
1 favored by entropy
2 favored by enthalpy (low heat)
Which matters more entropy or enthalpy
Depends on T
Define Gibbs free NRG and give symbols
A value used to predict whether ChangeH or ChangeS will determine rxn tendency
ChangeG KJ/Mol
What is the equation for Gibbs free NRG and another name
Change H - TChange S
Thermal dynamic eqn
What does Change G mean
Measures the combined effects of H and S at a specific T
If G is a - value rxn is spontaneous (exergonic)
If G is + rxn is non spontaneous (endergonic)
What if G is 0
Equilibrium