Chapter 17.1 Flashcards
Define heat
How does it flow and what is used to measure it
Sum total of the KE of all particles in a sample of matter
Flows from [high] to [low]
Define thermochemistry and give another name for it
The study of heat changes that accompany chemical rxns and physical changes
Thermodynamics
Describe a calorimeter and how it works
Contains h2o in an insulated vessel
Rxn occurs in a known mass of h2o
Heat absorbed or released by h2o = that absorbed or released by rxn
Data is t showing heT changes
Describe temperature and it’s units
Measures the average KE of particles in a sample of matter
Unit in joules which is the metric unit of heat or NRG
1J=kg m2/sec2
Define specific heat symbol and unit
Amount if heT NRG required to raise t of a substance by 1 c or K
Symbol is Cp
Units joules /g c
What has the highest specific heat and give an example
H2o
4.18 j/g c
Define heat capacity what are the three things it depends on
The ability of a material to absorb heat
- Material changing of T
- The mass
- Size if the change in t
Specific heat equation and variables
Cp= q/(m)change of T Cp= specific heat Q heat ab/re. J M mass g T. K
What’s another name for heat of rxn and define it
Enthalpy
The amount if heat absorbed or released in a chemical rxn or the difference in heat btw the stored NRG if the reactants and that if the products
What are the two possible values for enthalpy
Exothermic -heat released; feels hot
Change in H is beget ice as heat is lost
Reactants have a higher heat content than products
Endothermic - heat absorbed feels cold
Change in H is positive as heat is gained
Products have higher heat content
How do you calc enthalpy
ChangeH= Hproducts - Hreactants
When ChangeH is a high negative value…
Stable compound is forming spontaneously, vigorously
Large amounts of NRG released as products form
This is most common b/c reactants gain stability
When ChangeH is positive or low negative
Unstable compound may form and may decompose violently
Define heat of combustion
Heat released by the complete combustion of 1 mol of a substance