Chapter 17 (Oxidation/Reduction) Flashcards

1
Q

Oxidation

A

The loss of electrons Substance being oxidized is known as the reducing agent (because it starts off reduced)

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2
Q

Reduction

A

The gain of electrons Substance being reduced is known as the oxidizing agent (because it stars off oxidized)

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3
Q

Zn (arrow) Zn2+ + 2e-

A

Oxidation

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4
Q

Cu2+ + 2e- (arrow) Cu

A

Reduction

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5
Q

Catabolism is (oxidative/reductive)

A

oxidative

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6
Q

Anabolism is (oxidation/reductive)

A

reductive

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7
Q

Electrons can be transfered in four different ways

A
  1. Directly as e- 2. As a H atom (1e-) (H+) 3. As a hydride atom (2e-) (H-) 4. Through direct combination with O2
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8
Q

Many times in biological systems, the LOSE of an e- is associated with a lose of a ___ hence why the enzymes are called ___

A

Hydrogen Dehydrogenase’s

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9
Q

Most reduced form

A

Methane (CH4)

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10
Q

Most oxidized form

A

Carbon dioxide (CO2)

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11
Q

NAD+ is a biological (oxidizing/reducing) agent

A

oxidizing (becomes reduced)

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12
Q

When you turn a C-C into a C=C it involves using ___

A

FAD

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13
Q

Reduction potentials measure a compounds affinity for ___

A

electrons

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14
Q

The more (positive/negative) the standard reduction potential the more the compound wants electrons

A

positive = more wants electrons (wants to be reduced)

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15
Q

Equation for Delta Eº´

A

Acceptor - Donor

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16
Q

Equation for Delta Gº’

A

-nF(Delta Eº’)

17
Q

When Delta Eº’ is positive then Delta Gº’ is ___

A

negative (favorable)

18
Q

Equation for Delta E

A

Delta Eº - (RT/nF) x ln ([donor]/[acceptor])