Chapter 17 Key Terms Flashcards
Entropy
Measure of disorder
s=k(ln(W))
Free Energy of Formation
Change in free energy when 1 mol of a compound forms
Gibbs free energy
Thermodynamic state function relating enthalpy and entropy. Aka, potential
Irreversible Reaction
Reaction that does not achieve theoretical limit of free energy
Reversible reaction
Reaction that achieves theoretical limit of G, and can change direction at any change
Second Law of Thermodynamics
Entropy always increases
Spontaneous Process
Process that occurs without any external intervention
Standard Change in Free Energy
Change in G for a process when all reactants and products are in their standard states
Standard Entropy Change of Reaction
Change in entropy for a process wherein all reactants and processes are in standard states
Standard Molar Entropy
A measure of the energy dispersed into one mole of a substance at a T
Third Law of Thermodynamics
Entropy of a perfect crystal at 0 K is 0