Chapter 17 chemical equilibrium Flashcards
reversible reaction
one in which the products react back to give the
reactants
chemical equilibrium
a state of dynamic balance in a reversible reaction where the forward/backward rate of reaction is the same
dynamic state
the reactants are continuously making products and the products are continuously making reactants
le chartelier’s principal
states that if stress(temp. concentration, pressure) is applied to a system at equilibrium the system re-adjusts to relieve the stress applied
(effect) when… to an eq. system : pressure increased
equilibrium shifts to the side with a lower no. of
molecules
(effect) when… to an eq. system : pressure decreased
equilibrium shifts to the side with a higher no. of molecules
(effect) when… to an eq. system : temp inc.
endothermic reaction is favored
(effect) when… to an eq. system : temp dec.
exothermic reaction is favored
(effect) when… to an eq. system : concentration of x inc.
reaction that removes x is favored
(effect) when… to an eq. system : concentration of x
dec.
reaction that forms x is favored
le chatlier principal : ammonia
conditions under which the Harber process is carried out are a compromise between yield of ammonia , time, cost/safety (low temp, high pressure= not viable)
le chatlier principal :sulphuric acid
conditions for the contact process are a compromise rather than based strictly on the principal (low temp. high pressure[liquefy the SO2] = not viable)