Chapter 12 acids and bases Flashcards
Arrhenius theory of acids and bases + equations
acids = substance that dissociates in water to produce h+ ions (strong = completely dissociates , weak = slightly disassociates ) {HA + H2O = H3O+A- } Bases = substance that dissociates in water to produce OH- ions[hydroxide ions] ( strong = completely , weak= slightly)
shortcomings of Arrhenius theory (3)
it is hydronium ions rather than bare H+ ions suggested ny arrhenius , htat exist in solution, definitions restricted to aqueous solutions(not inc. benzene,ammonia) , not all acid base reactions require water (eg ; ammonia and hydrogen chloride gas )
Bronsted Lowry Theory
Acid = proton donor ( strong=good , weak= poor) Base = proton acceptor (strong=good , weak=poor)
Substance that can act as an acid/base
amphoteric/amphiprotic
Comparing both theories
ARH - limited to reactions in water B&L is not , ARH - limited to bases that produce hydroxide ions in water but not all do , Substances that would not be classified as acids/bases by ARH are classified by B&L (eg;NH3) , ARH cannot explain how a substance can be amphoteric
Conjugate acid-base pair
Any pair consisting of an acid and a base that differ by one proton (if + on right then - on left and vice versa)
Acid/base change to what conjugate
base= to conjugate acid when accepts a proton, Acid= to conjugate base when it donates a proton
Neutralization
Acid + base = salt + water
Salt (definition)
substance formed when the H ion from an acid is replaced by a metal /ammonium ion
Examples of neutralization in our everyday lives (4)
medication - antacids for excess Hydrochloric acid , Agriculture - lime for acidic soils
Environmental - in areas that suffer from acidic rain limestone is added to lakes Miscellaneous - toothpaste is slightly basic to neutralize acidic foods that cause tooth decay, shampoo is slightly basic and hair conditioner is slightly acidic