Chapter 15 (one five) fifteen - Acid-Base Equilibria Flashcards

1
Q

rate this chapter

A

bad

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2
Q

Can you ever put “partners” on the same side of an equilibrium reaction equation?

A

No

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3
Q

What things must a buffer have>

A
  1. A weak acid
  2. A partner within a factor of 10 of the WA (has to be an ionic salt)
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4
Q

What are “partners?”

A

Partners are the same molecule with a difference in one H+ ion (ex. NH3 weak base and NH4 conjugate acid)

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5
Q

What is a buffer?

A

Substance that resists change in pH

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6
Q

What units can you work with in buffer questions?

A

moles or mmol

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7
Q

WHen is the only time the Henderson-Hasselbach Equation applies?

A

In the case of a buffer (WA or WB + partner, either or and you get nothing)

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8
Q

What proportion of partners is the ideal buffer?

A

1:1

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9
Q

What are the units of the H-H equation’s A-/HA?

A

Moles, put in molarity it just cancels to moles, H-H equation uses proportion

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10
Q

What is pH a measure of? How do higher and lower pH sol’ns react?

A
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11
Q

How do you calculate % dissociation?

A
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12
Q

Is OH- a strong or weak base?

A
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13
Q

Is H2O a strong or weak acid?

A
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14
Q

H-H equation for bases

A
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15
Q

Why aren’t spectator ions included?

A
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16
Q

What unit do you need of a substance for a -log pH calculation?

A

Mol/L

17
Q

Why do weak-base titrations have a lower equivalence than strong-base titrations?

A

Because as the reactants neutralize each other 100% (strong acid/base reacts with weak acid/base), the remaining salt hydrolyzes and creates either H+ or OH-

18
Q

Define titrate

A

Add a reagent/titrant until substance being measured is exactly fully reacted