Chapter 12 - Chemical Analysis Flashcards
what is meant by purity in chemistry?
A pure substance is one that is made up of just one substance. The substance can be either an element or a compound
what is meant by purity in everyday terms?
‘has nothing added to it’ and it is in its natural state
what are fixed points
The melting and boiling points of an element or a compound
how can you identity a pure substance
it has a fixed point
how can you identify a mixture
it doesn’t have a fixed point. the melting and boiling point of the mixture varies.
define formulation
a mixture with components in fixed ratios that has been designed as a product
give 3 examples of everyday formulations
mixed paints, cakes, medicine
how to calculate the Rf value
Rf = distance moved by the substance/distance moved by the solvent
give an example of a mobile phase in chromatography
water (solvent)
give an example of a stationary phase in chromatography
paper
what is the test for hydrogen
a lit split —-> squeaky pop
what is the test for oxygen
a glowing splint —-> relights in the presence of oxygen
what is the test for chlorine
damp blue litmus paper —–> bleaches white
what is the test for carbon dioxide
limewater —–> turns cloudy
2 ways to test for positive ions
flame tests and adding sodium hydroxide
test for lithium ions
flame test —-> crimson
test for copper ions
flame test —-> green
sodium hydroxide ——> blue precipitate
test for calcium ions
flame test —-> orange-red
sodium hydroxide ——> white precipitate
test for sodium ions
flame test —-> yellow
test for potassium ions
flame test —-> lilac
test for iron (III) ions
sodium hydroxide ——> brown precipitate
test for iron (II) ions
sodium hydroxide ——> green precipitate
test for magnesium
sodium hydroxide ——> white precipitate
test for aluminum ions
sodium hydroxide ——> white precipitate (dissolves in excess sodium hydroxide)
test for sulfate
add hydrochloric acid and barium chloride
—–> white precipitate
test for chloride (halides)
add nitric acid and silver nitrate —-> white precipitate
test for bromide (halides)
add nitric acid and silver nitrate —-> cream precipitate
test for iodide (halides)
add nitric acid and silver nitrate —-> yellow precipitate
test for carbonates
add acid —-> fizzes
benefits of instrumental tests
faster
more accurate
more sensitive
benefits of flame emission spectroscopy
works with mixtures
brighter line
more concentrated