Chapter 11 - Mirco-structure and Metallography | Iron-Carbon Alloys Flashcards
Alloys
Mixture of metals or mixture of metal and another element.
Steel
alloy of steel and carbon.
Microstructure & Properties of Plain Carbon Steels
Fe-C Diagram
- Great variability in the microstructures we form in steels ( due to various phases)
Fe-C Phase Diagram
allows us to process alloys by conrol temperature & Concentration of Fe & C
Pure Iron 1
Solidification form at 1534 degrees: BCC Phase δ
Pure Iron 2
2 Polymorphic changes (first: 1400ºC, FCC austentite γ phase; then at 910ºC, BCC ferrite a phase
Pure Iron 3
Max solubility of C in δ, γ and α is 0.1, 2.0, & 0.02 wt.%
Pure Iron 4
Alloys with C content <2.06 wt.% = Steels
C content > 2.06 wt.% = Cast Irons
Majority of Commercial steels have < 1wt.%
Ferrite
α solid solution of small amount of Carbon dissolved in α (BCC) iron.
Stable form of iron below 912°C
Softest structure on Phase diagram
Ferrite 2
Tensile Strength = 2.75x107 Pa
Elongation = 40% in 2 in
Hardness = > Rockwell C 0 or
> Rockwell B 90
Austentite 1
solid solution of Carbon dissolved in gamma (FCC) iron
High Formability
Normally not stable at room temperature.
Austentite 2
- Tensile strength = 1.03x109 Pa
- Elongation = 10% in 2 in
- Hardness > Rockwell C 40
Cementite 1
AKA Iron Carbide
Very hard, brittle intermetallic compound (6.67% C)
Low tensile strength (approx. 3.44x107 Pa)
High Compressive strength
Ledeburite
mixture of astentite and cementite
formed at 1130°C & contains 4.3% C
Pearlite
Mixture of ferrite & cementite
0.80% C and is formed at 723°C
Pearlite 2
Tensile strength = 8.27 x108 Pa Elongation = 20% in 2 in • Hardness = Rockwell C 20 or Rockwell B 95-100 or BHN 250-300
Formation of pearlite
1) You have austentite
2) Cementite Nucleus Grows on A Boundary
3) Ferrite grows either side of C Nucleus
4) Expands up and out the way until all austentite is covered.
Martensite
Super saturated solution of carbon in ferrite
Martensite Formation
Formed when steel is cooled so quickly that the change from austentite to pearlite is suppressed.
Martensite 2
The interstitial carbon atoms distort the BCC ferrite
into a BC-tetragonal structure (BCT).; responsible
for the hardness of quenched steel
• Needlelike structure
Phase: Ferrite
Crystal Structure: BCC
Characteristics: Soft, Ductile, Magnetic
Phase: Austentite
Crystal Structure: FCC
Characteristics: Soft, Moderate Strength, Non-Magnetic
Phase: Cementite
Crystal Structure: Compound of FE & C - Fe3C
Characteristics: Hard & Brittle
Carbon Content: 0.01 - 0.1
Soft, ductile, can be work hardened but not heat hardened, weldable,
Used where high formability is needed
Carbon Content: 0.1 - 0.25
Soft, ductile, hardened by normalizing, work hardened, weldable, Ductile-Brittle transition just below room temp
General engineering uses for a mild steel
Carbon Content: 0.25- 0.6
Very Strong, heat treating produces a wide range of properties, Difficulte to weld, brittle below room temp
used for bars and forgings: rods, springs, hammers & axles shafts
Carbon Content: 0.6 - 0.9
Strong (without being heat treated, Ductility will be lower with less carbon
Used for Max strength items (tools, wear resistant components)
Carbon Content: 0.9 - 2.0
Wear resistant (V hard = less tough & ductile), No welding, tend to be brittle Used for cutting tools; wood chisels, files and saw blades.