Chapter 11- Internal Energy, Absolute Zero And Change Of State Flashcards

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1
Q

Heat def

A

The transfer of energy as a result of the random interchange of energy between two bodies in thermal contact, resulting in energy flowing from hot to cold

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2
Q

Work def

A

The energy transfer produced by the action of a macroscopic force

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3
Q

Internal energy def

A

The sum of the kinetic energy and the bond potential energies of all the molecules in the system

U= KE+ PE

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4
Q

Ideal gases is when…

A

No intermolecular forces are at work so the bond potential energy is 0

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5
Q

First law of thermodynamics

A

The internal energy of a system can only change by exchanging energy with its surroundings, either by doing work or by heating

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6
Q

🔺W >0 when

A

Work is done on the system

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7
Q

🔺W< 0 when

A

Work is done by the system

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8
Q

First law of thermodynamics eq

A

🔺U = 🔺W + 🔺H

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9
Q

When 🔺H< 0

A

The system is cooled

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10
Q

When 🔺H > 0

A

Then the system is heated

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11
Q

If temperature doesn’t change then…. 🔺U

A

🔺U = 0

U= KE + PE

The KE is temperature dependent

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12
Q

Liquid to gas

A

Evaporation

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13
Q

Gas to solid

A

Deposition

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14
Q

Solid to liquid

A

Melting

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15
Q

Liquid to solid

A

Solidification

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16
Q

Solid to gas

A

Sublimation

17
Q

Gas to liquid

A

Condensation

18
Q

Latent heat def

A

The amount of energy released of required for a change of state to occur without a change in temperature

19
Q

Specific latent heat of FUSION

A

Energy required per unit mass to change a SOLID to a LIQUID without a change in temperature

20
Q

Specific latent heat of VAPORISATION

A

The energy per unit mass required to change the state of a LIQUID into a VAPOUR without a change in temperature

21
Q

Energy equation for latent heat

A

E= m(mass) x L(specific latent heat)

22
Q

Specific latent heat unit

A

Jkg^-1

23
Q

A graph shape during a state change

A
Stays stationary (straight line above time axis) 
All work being done is being used to increase PE not KE
24
Q

Absolute zero definition for an ideal gas

A

The temperature at which an ideal gas has zero volume

The temperature at which the particles of a system have zero kinetic energy

25
Q

Gases differ with three characteristics

A
  • volume
  • temperature
  • pressure
26
Q

Absolute zero def

A

The lowest temperature that can theoretically exist and is given a temperature of 0 Kelvin

27
Q

What is zero-point energy?

A

The energy at absolute zero
Due to quantum fluctuations
Which are irrespective to temperature
Since 🔺E is never zero, there will always be fluctuations in the energy value