Chapter 1.1 Flashcards

1
Q

what shape is s orbitals

A

sphere shaped

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2
Q

what can determine an atomic orbitals preferred shape

A

there corresponding quantum numbers and the use of a wavelength

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3
Q

what do atomic orbitals represent

A

the area around the nucleus where the electrons are most likely to be

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4
Q

war is probability distribution

A

where the electrons are most likely to be

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5
Q

what shape are p orbitals

A

they are often referred to as dumbbell shaped

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6
Q

what is a nodal plane

A

it splits the orbitals into two differently phased lobes on either side of the nucleus

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7
Q

what is phase on a “p” orbital

A

it represents the sign of the function for that area (+/-)

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8
Q

what role does “phase” play in a p orbital

A

it plays a role in bonding

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9
Q

how many equal levels is there in “p” orbitals

A

3

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10
Q

in the p orbital how do the 3 levels line up to eachother

A

they are orthogonal (perpendicular with respect to eachother) and most viewed alighned with the coordinate axes

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11
Q

what rules arise from the quantum spin number and pauli exclusion principal

A

each orbital may hold a max of two spin-paired electrons
ie.. s orbials may hold up to 2 electrons and each 3p may hold up to 2 electrons

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12
Q

what is the pauli exclusion principal

A

no two electrons can have the same 4 quantnum numbers

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13
Q

what are the quantum numbers

A

the n, l, m1, ms

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14
Q

what order do electrons like to fill orbitals

A

in order of increasing energy
ie.. 1s, 2s, 2p

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15
Q

what is being degenerate

A

a set of orbital with exactly the same energies

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16
Q

can orbitals ever have the same energy levels

A

yes
ie.. 2px 2py 2pz

17
Q

what are the two categories you can divide orbitals in systems into

A

valence and core orbitals

18
Q

what is a core orbital

A

fully occupied orbitals of the lowest energy and electrons in them are core electrons

19
Q

what are the characteristics of core electrons

A

they are low in energy (stable) and close to the nueclus

20
Q

what are valence orbitals

A

they are high energy orbitals. orbitals can be vacant, semi occupied, and filled

21
Q

what are some characteristics of valence orbitals

A

high in energy (less stable), and further from the nucleus

22
Q

what kind of orbital is involves with chemical bonding and reactivity

A

valence orbitals

23
Q

for the first few groups how does the number of valence e- correspond with the elements group number

A

valence e- = group #

24
Q

what are the two primary forms of chemical bonding between atoms

A

ionic and covalent

25
Q

how are valence orbitals distributed in an ionic bond

A

valence electrons are fully transferred from ones valence orbitals to anothers

26
Q

when atoms gain or loose electrons how does that effect them

A

the loss of an electron makes that atom cationic and the gain of and electron makes the atom anionic

27
Q

what are covalent bonds with positive and negative charges commonly referred to as

A

salts

28
Q

what are covalent bonds

A

they are when two semi occupied valence orbitals overlap and combine to form a fully occupied molecular orbital

29
Q

in a covalent bond situation how cant the bond between them be though of

A

two nuclei where the two electrons are being shared between them