Chapter 1.1 Flashcards

1
Q

what shape is s orbitals

A

sphere shaped

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2
Q

what can determine an atomic orbitals preferred shape

A

there corresponding quantum numbers and the use of a wavelength

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3
Q

what do atomic orbitals represent

A

the area around the nucleus where the electrons are most likely to be

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4
Q

war is probability distribution

A

where the electrons are most likely to be

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5
Q

what shape are p orbitals

A

they are often referred to as dumbbell shaped

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6
Q

what is a nodal plane

A

it splits the orbitals into two differently phased lobes on either side of the nucleus

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7
Q

what is phase on a “p” orbital

A

it represents the sign of the function for that area (+/-)

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8
Q

what role does “phase” play in a p orbital

A

it plays a role in bonding

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9
Q

how many equal levels is there in “p” orbitals

A

3

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10
Q

in the p orbital how do the 3 levels line up to eachother

A

they are orthogonal (perpendicular with respect to eachother) and most viewed alighned with the coordinate axes

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11
Q

what rules arise from the quantum spin number and pauli exclusion principal

A

each orbital may hold a max of two spin-paired electrons
ie.. s orbials may hold up to 2 electrons and each 3p may hold up to 2 electrons

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12
Q

what is the pauli exclusion principal

A

no two electrons can have the same 4 quantnum numbers

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13
Q

what are the quantum numbers

A

the n, l, m1, ms

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14
Q

what order do electrons like to fill orbitals

A

in order of increasing energy
ie.. 1s, 2s, 2p

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15
Q

what is being degenerate

A

a set of orbital with exactly the same energies

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16
Q

can orbitals ever have the same energy levels

A

yes
ie.. 2px 2py 2pz

17
Q

what are the two categories you can divide orbitals in systems into

A

valence and core orbitals

18
Q

what is a core orbital

A

fully occupied orbitals of the lowest energy and electrons in them are core electrons

19
Q

what are the characteristics of core electrons

A

they are low in energy (stable) and close to the nueclus

20
Q

what are valence orbitals

A

they are high energy orbitals. orbitals can be vacant, semi occupied, and filled

21
Q

what are some characteristics of valence orbitals

A

high in energy (less stable), and further from the nucleus

22
Q

what kind of orbital is involves with chemical bonding and reactivity

A

valence orbitals

23
Q

for the first few groups how does the number of valence e- correspond with the elements group number

A

valence e- = group #

24
Q

what are the two primary forms of chemical bonding between atoms

A

ionic and covalent

25
how are valence orbitals distributed in an ionic bond
valence electrons are fully transferred from ones valence orbitals to anothers
26
when atoms gain or loose electrons how does that effect them
the loss of an electron makes that atom cationic and the gain of and electron makes the atom anionic
27
what are covalent bonds with positive and negative charges commonly referred to as
salts
28
what are covalent bonds
they are when two semi occupied valence orbitals overlap and combine to form a fully occupied molecular orbital
29
in a covalent bond situation how cant the bond between them be though of
two nuclei where the two electrons are being shared between them