1.5 Hybrid Orbitals Flashcards

1
Q

what creates stronger bonds in orbitals

A

the better overlap between the orbitals the stronger the bond

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2
Q

what do bond involve

A

the sharing of spin-paired electrons

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3
Q

in organic chem what is the most common valence orbitals available

A

S and P

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4
Q

what is hybridization

A

it is a simple theory that can help explain why geometry can be linear, trigonal plainer, or tetrahedral

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5
Q

what is hybridization orbitals

A

S and P orbitals overlapping

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6
Q

if we have a carbon (valence e is 2S2, 2P2) and hybridization occurs what happens to the configuration

A

it becomes sp3 this means one s + 3p (25% s and 75% p) and all _ _ _ _s get filled with electrons and moved to the same heights. and we call this atom 3 P hybridized

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7
Q

if we combine 2s orbitals with the 2p, 2p, 2p orbitals we get…

A

four sp3 orbitals distributed in a tetrahedral

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8
Q

how many lobes do SP3 orbitals have

A

the combination of the s and the p orbitals cause it to has 2 lobes like p orbitals but one is smaller then the other

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9
Q

what kind of hybridization can pi bonding be explained

A

by sp2 hybridization

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10
Q

if a atom is sp2-hybridized how many orbitals does it have and what are they made from

A

it has 3 orbitals made from one s and two p orbitals

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11
Q

what is the precent compisition of sp2-hybridized orbitals

A

they are 33.3% s and 66.6% p

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12
Q

what has more energy sp3 or sp2

A

sp3

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13
Q

explain how the electrons fill when there is a sp2 hybridization

A

there is sp2 _ _ _ with one arrow (these are hybridized
and there is a 2p _ with a arrow (this is not hybridized)

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14
Q

in a sp2 hybridization are all orbitals hybridized

A

no there is one unhybridized p orbital

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15
Q

what kind of bonds does sp2-hybridized allow for

A

the formation of double bonds if 2 p orbitals each with electron are on atoms connected by a sigma bond

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16
Q

if we combine the 2s orbitals with the 2px, 2py we get…

A

three sp2 orbitals (and keep 2pz)

17
Q

for the sp2 hybridization what do the orbitals look like

A

the three sp2 have two lobes (one bigger, one smaller) and they are distributed in a trigonal planer

the un hybridized p orbital does not change (2 same sized lobes)

18
Q

what is they hybridization of methane (CH4)

A

sp3

19
Q

what is the hybridization of ethylene (C2H4)

A

sp2

20
Q

in ethylene (C2H4) explain how the structure creates double bonds

A

there is 2 tetrahedral shape of hybridized sp2 carbon orbitals and they over lap creating a sigma bond

there is 2 un hybridized p bonds that hover electrons causing pi bonds

these two bonds create double bonding

21
Q

if we combine the 2s orbital and the 2px orbital we get…

A

two sp orbitals (and keep the 2py and 2pz)

22
Q

describe the shape of a sp orbital

A

the two sp hybrids would have two lobes one bigger then the other

the un hybridized 2py and 2pz will have two same sized lobes

23
Q

what are the anges between the new sp hybridized orbitals

A

they are 180 degrees so the geometry is linear

24
Q

list the charictrisitc of an orbital with 2 groups

A

-it (can/has?) have a triple bond
-its linear
-it is sp hybridized
-2=1+1

25
Q

list the characteristics of an orbital with 3 groups

A

-it (can/has?) have a double bond
-its trigonal planar
-it is sp2 hybridized
-3=1+2

26
Q

list the characteristics of an orbital with 4 groups

A

_