Chapter 11 Flashcards

1
Q

Dispersion Forces (London Forces):

A

Result of fluctuations in Electron distribution within atoms/molecules. Weakest IMF!

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2
Q

What does IMF stand for? Mhmm

A

Intermolecular Forces.

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3
Q

Dipole-Dipole Force:

A

Exists between Polar molecules; with one Electron rich region, 1 region e- poor. Boiling points increase with increasing dipole-dipole moments.

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4
Q

Hydrogen Bonding:

A

“Super dipole-dipole,” one of strongest IMF. H must be bonded to N, O, F. We also have London and dipole-dipole IMF with H-bonding.

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5
Q

Ion-Dipole Force:

A

When ionic compound is mixed with Polar compound. Positive end of polar molecule attracted to negative ion, vice versa.

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6
Q

Surface Tension (of a liquid):

A

Not sure important??? Energy required to increase surface area by 1 unit amount. Stronger IMF= stronger surface tension.

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7
Q

Viscosity:

A

The resistance of a liquid to flow. Stronger IMF= stronger viscosity. Also Molecular structure; more branching/length of structure=more viscous.

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8
Q

Capillary Action:

A

a liquids’ ability to resist flow of gravity into a tube.

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9
Q

Cohesive VS Adhesive Forces;

A

Cohesive: attraction between molecules in liquids.
Adhesive: attraction between surface of a tube and liquid molecules.

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10
Q

What is vaporization?

A

a state change from liquid to gas. The higher the temp, the greater the thermal energy.

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11
Q

Vapor Pressure: look at book too!

A

Is a measure of the tendency of a material to change into the gaseous or vapor State

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12
Q

What is Dynamic Equilibrium?

A

When the rate of evaporation = the rate of condensation.

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13
Q

Heat of Vaporization:

A

Energy required to vaporize one mole from liquid to gaseous state. TEMP dependent!!!

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14
Q

What is a boiling point?

A

The temperature at which the vapor pressure of the liquid equals the environmental pressure surrounding the liquid.

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15
Q

How to use the Clausius-Clapeyron Equation?

A

Look at the equation as y=mx+b! look into the equation in book. Two-point system is more straight forward.

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16
Q

Sublimation, Heat of Sublimation:

A

The transition from solid to gas. The heat of sublimation= heat of fusion + heat of vaporization.

17
Q

Fusion, Heat of Fusion:

A

The transition from solid to liquid. Heat of fusion: energy required to melt 1 mole of a solid.

18
Q

Heating Curve, how to solve them:

A

Page 515!!! look it over, 100% a big point problem on it on exam.

19
Q

What are Phase Diagrams?

A

Map of state/phase of a substance as a function of pressure and temp. Water is unique!!!