Ch11 Flashcards

1
Q

solids behavior

A

locked in place and vibrate

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2
Q

what is special about water

A

it is more dense as liquid than solid

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3
Q

gas properties density shape volume and intermolecular forces

A

low density indefinite shape indefinite volume weak forces

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4
Q

liquid density shape vol intermolecular forces

A

high density indeterminate shape definite volume moderate bonds

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5
Q

solid density shape volume and intermolecular forces

A

high density definate shape and definate volume and strong intermolecular bonds

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6
Q

can liquids be compressed

A

no because they’re already compact together

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7
Q

crystalline solid

A

solid with patterns in long range repeating order

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8
Q

amorphous solid

A

random solid with no repeating order

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9
Q

what can change state of matter besides temperature

A

pressure

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10
Q

dispersion forces

A

occour because of instantaneous dipole moments because of functions in electron cloud of atoms and molecules

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11
Q

relationship between boiling point and molar mass

A

boiling point increases as molar mass increases

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12
Q

how do polar molecules compare to non polar molecules with boiling point

A

they have higher melting and boiling point

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13
Q

where can you find hydrogen bond

A

in polar molecules that contain H bond directly to F O N

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14
Q

what affect does hydrogen bond have on boiling and melting point

A

highly increases them

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15
Q

why do protons and electrons bond to eachother

A

potential energy decreases when they do

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16
Q

what are stronger intermolecular forces or bonding forces

A

bonding

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17
Q

what are bonding forces

A

large charges over small distanxes

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18
Q

what are intermolecular forces

A

small charges over large distance

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19
Q

relationship with dispersion force and molar mass

A

increases with molar mass

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20
Q

why does molar mass increasing affect disp force

A

larger particles have more things to stick to

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21
Q

dipole dipole bonds

A

an intermolecular force exhibited by polar molecules which results from uneven charge distribution

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22
Q

permanent dipole

A

seperation of charge where one end is slightly negative and the other is positive

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23
Q

miscability

A

ability for substances to mix without separating into two phases

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24
Q

can polar substances mix with nonpolar substances

A

nonpolar things mix with polar things non polar things mix with nonpolar things

25
ion dipole force
intermediate force between ion and opposite charges end of polar molecule
26
what is strongest intermolecular bond
ion dipole
27
where do intermolecular bond forces happen
in empty space between atoms
28
what is surface area
amount of energy required to increase surface area by unit amount
29
surface tension
energy required to penetrate top layer of liquid
30
viscosity
resistance of liquid to flow
31
viscosity units
gs per cm s
32
capillary action
ability for water to flow up against gravity
33
what does concave meniscus mean
liquid more attracted to container
34
what does convex meniscus mean
liquid more attracted to itself
35
what is vaporization
transition from liquid to gas
36
what is gas to liquid
condensation
37
two reasons spilled water evaporates fast
less things holding it together and larger surface area
38
meaning of volatile
vaporizes easily
39
meaning of nonvolatile
doesn’t want to vaporize
40
what increases rate of vaporization
temperature
41
which molecules are the first to evaporate
the ones with most kinetic energy
42
is vaporization or condensation exothermic
vapor exp condensation endo
43
what is heat of vaporization
energy required to vaporize a mole of a liquid to a gas
44
what is dynamic equilibrium
when rate of forward reaction equals backward reactiin
45
what is vapor pressure correlated with
pressure, temp, surface area,and magnitude of intermolecular forces
46
what is vapor pressure
the pressure of gas in dynamic equilibrium with its liquid
47
boiling point
temperature that vapor pressure equals external pressure
48
what is boiling point
temperature at which vapor pressure is 1atm
49
claudia clapton equation
ln Pvap = -change in heat/ r * 1/T+lnB
50
crit temp
temperature at which liquid cannot exist
51
crit pressure
pressure to get liquid to unit temp
52
supercritical liquids
characteristics of both liquid and gas and act as good solvent
53
sublimation
molecules with too much thermal energy moving from solid to gas
54
deposition
gas molecules colliding with solids and getting trapped by their intermolecular fields
55
melting point
temp that solids have enough kin energy to become liquids
56
melting/fusiin
going from solid to liquid
57
heat fusiion
is heat required to melt a mop of solid
58
phase diagram
for a given substances shows when it will be what form of matter
59
triple point
3 states of mater are stable at equilibrium