Ch 9 Flashcards

1
Q

Energy

A

capacity to do work or produce hear

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2
Q

how is energy transfered

A

by work (force*displacement)

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3
Q

two main forms of energy

A

potential and kinetic

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4
Q

kinetic energy

A

energy due to motion

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5
Q

potential energy

A

energy due to position or composition

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6
Q

what is a system in a chemical equation

A

the molecules

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7
Q

first law of thermodynamics

A

total energy in universe is constanr

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8
Q

internal energy

A

sum of kinetic and potential energy in system

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9
Q

what is state function

A

property independent or pathway

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10
Q

state functions examples

A

temerature, pressure, concentrations, phase of matter, and internal energy

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11
Q

how do you find Change in energy of system

A

it is the negative change in surrounding energy

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12
Q

symbol for heat

A

q

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13
Q

symbol for work

A

w

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14
Q

how to find change in system energy

A

heat+ work

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15
Q

what does the sign of a mean

A

when positive it means system is endothermic, if it is negative it means system is exothermic

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16
Q

exothermic

A

energy released, hot to touch

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17
Q

endothermic

A

heat absorbed, cold to touch

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18
Q

what does sign of w mean

A

negative means work is done by system, when positive it means work is done to it

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19
Q

i what unit is measurement for thermal energy

20
Q

how to find q equations

A

mass x heat capacity x change in temp

21
Q

specific heat capacity

A

amount of energy required to increase temp of 1g of substance

22
Q

expansion

A

work done by a gas +

23
Q

compression

A

work done to a gas -

24
Q

what does it mean if change in vol is 0

25
calorimetry
measure or heat transfer
26
t or f using a calorimeter causes equations to change
false
27
enthalpy
the amount of heat transferred under constant pressure
28
enthalpy symbol
H
29
equations for enthalpy
H = E+PV
30
what is change in enthalpy equal to
heat of products
31
Work equation
w = p x change in volune
32
when manipulating a reaction with delta H what happens to delta H
same thing that happens to equation
33
Hess’s law
if steps describe a reaction the sum of their delta h is equivalent
34
how does a change in potential happen in chem reactions
when bonds are broken
35
does breaking a bond require energy or does making one require it
breaking a bond requires energy
36
how to find delta h for chem reaction
summing up bonds broken plus bonds created
37
standard state for gas
pure substance 1 atm pressure
38
standard state for liquid or solid
1 atm and 25 deg celcius
39
standard state for aq
1 M concentration
40
what does a bomb calorimeter ensure
reactions occur at constant volume
41
what bonds are broken and formed in ending thermos reaction
weak are broken and strong form
42
what bonds are broken and formed in exothermic reaction
strong broken and weak formed
43
what is standard enthalpy of formation
energy for when a mop of compound forms from constituent elements in standard states
44
how to calc change in enthalpy of reaction
sum of prod bonds - sum of react bonds multiply all by their coefficients
45
born havre cycle
a series of steps based on hess law that represent formation of ionic compounds and constituent elements
46
how to find lattice energy
sum of energies after using born janet cycle